Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 2, Problem 12P
Draw charge-separated resonance structures to give a representation of the bonding in
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Are there any alternative methods better than the MOHR titration to quantitatively determine salt in a sample?
hybridization of nitrogen of complex molecules
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
00
rise
☐ x10
fall
yes
no
☐ atm
G
Ar
1
Chapter 2 Solutions
Inorganic Chemistry
Ch. 2 - Draw Lewis structures to describe the bonding in...Ch. 2 - Use the Lewis structure model to deduce the type...Ch. 2 - Draw the resonance structures for the O3 molecule....Ch. 2 - 2.4 Draw Lewis structures for (a) , (b) ,(c) and...Ch. 2 - 2.5 Each of the following is a radical. For which...Ch. 2 - (a) Use VB theory to describe the bonding in the...Ch. 2 - 2.7 Use VB theory and Lewis structure model,...Ch. 2 - 2.8 Does VB theory indicate that the diatomic...Ch. 2 - 2.9 (a) Use MO theory to determine the bond order...Ch. 2 - Prob. 10P
Ch. 2 - Prob. 11PCh. 2 - Draw charge-separated resonance structures to give...Ch. 2 - Prob. 13PCh. 2 - In the following table, match a species in list 1...Ch. 2 - Using the data in table 2.2, determine which of...Ch. 2 - Prob. 16PCh. 2 - 2.17 Use the VSEPR model to predict the structures...Ch. 2 - 2.18 Use the VSEPR model to rationalize the...Ch. 2 - Determine the shapes of each of the following...Ch. 2 - 2.20 State whether you expect the following...Ch. 2 - 2.21 (a) Draw resonance structure for the CO,...Ch. 2 - Prob. 22PCh. 2 - Prob. 23PCh. 2 - Suggest reasons for the following observations....Ch. 2 - Prob. 25PCh. 2 - Prob. 26PCh. 2 - 2.27 (a) Write down the ions that are present in...Ch. 2 - 2.28 Assuming that VSEPR model can be applied...Ch. 2 - Critically compare the VB and MO treatments of the...Ch. 2 - The table below gives the average composition of...Ch. 2 - Carbon monoxide is a toxic pollutant which arises...Ch. 2 - 2.32 Volcanoes and deep sea hydrothermal vents are...
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