(a) Interpretation: The number of significant digits in the answer should be determined by evaluating the given expression. ( 149.2 + 0.034 + 2000.34 ) . Concept Introduction: During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy. Decimal place is the position of digit right to the decimal point. In division and multiplication, the calculated values are always rounded up to minimum number of significant figures. Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations. Rules for rounding off numbers are as follows: If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up. If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
(a) Interpretation: The number of significant digits in the answer should be determined by evaluating the given expression. ( 149.2 + 0.034 + 2000.34 ) . Concept Introduction: During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy. Decimal place is the position of digit right to the decimal point. In division and multiplication, the calculated values are always rounded up to minimum number of significant figures. Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations. Rules for rounding off numbers are as follows: If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up. If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Solution Summary: The author explains that the number of significant digits in the answer should be determined by evaluating the given expression.
The number of significant digits in the answer should be determined by evaluating the given expression.
(149.2+0.034+2000.34).
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Interpretation Introduction
(b)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
(1.0322×103+4.34×103)
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Interpretation Introduction
(c)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
4.03×10−2−2.044×10−3
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Interpretation Introduction
(d)
Interpretation:
The number of significant digits in the answer should be determined by evaluating the given expression.
2.094×105−1.073×106
Concept Introduction:
During addition or subtraction, the final answer should be rounded off for minimum number of digits after the decimal for more accuracy.
Decimal place is the position of digit right to the decimal point.
In division and multiplication, the calculated values are always rounded up to minimum number of significant figures.
Initially the calculation is carry out without considering the significant figures, the rounding off is done after the completion of all the calculations.
Rules for rounding off numbers are as follows:
If the number to be rounded off is followed by digit 5 or greater than 5, the number will be rounded up.
If the number to be rounded off is followed by digit zero or less than 5, the number will be rounded down.
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
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