
a)
Interpretation:
A structure for ketone or aldehyde with the following descriptions is to be proposed.
C4H7ClO, IR: 1715 cm-1; 1HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).
Concept introduction:
In 1HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.
To purpose:
A structure for ketone or aldehyde with the following descriptions.
C4H7ClO, IR: 1715 cm-1; 1HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).
b)
Interpretation:
A structure for ketone or aldehyde with the following descriptions is to be proposed.
C7H14O, IR: 1710 cm-1; 1HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).
Concept introduction:
Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm-1 and 2800-2860 cm-1. Saturated aldehydes absorb near 1730 cm-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm-1. Saturated ketones and cyclohexanones absorb near 1715 cm-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm-1. Cyclopentanones absorb around 1750 cm-1.
In 1HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.
To purpose:
A structure for ketone or aldehyde with the following descriptions.
C7H14O, IR: 1710 cm-1; 1HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

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Chapter 19 Solutions
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- + C8H16O2 (Fatty acid) + 11 02 → 8 CO2 a. Which of the above are the reactants? b. Which of the above are the products? H2o CO₂ c. Which reactant is the electron donor? Futty acid d. Which reactant is the electron acceptor? e. Which of the product is now reduced? f. Which of the products is now oxidized? 02 #20 102 8 H₂O g. Where was the carbon initially in this chemical reaction and where is it now that it is finished? 2 h. Where were the electrons initially in this chemical reaction and where is it now that it is finished?arrow_forward→ Acetyl-CoA + 3NAD+ + 1FAD + 1ADP 2CO2 + CoA + 3NADH + 1FADH2 + 1ATP a. Which of the above are the reactants? b. Which of the above are the products? c. Which reactant is the electron donor? d. Which reactants are the electron acceptors? e. Which of the products are now reduced? f. Which product is now oxidized? g. Which process was used to produce the ATP? h. Where was the energy initially in this chemical reaction and where is it now that it is finished? i. Where was the carbon initially in this chemical reaction and where is it now that it is finished? j. Where were the electrons initially in this chemical reaction and where is it now that it is finished?arrow_forwardRank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. OCH 3 (Choose one) OH (Choose one) Br (Choose one) Explanation Check NO2 (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Aarrow_forward
- For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forwardRank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check Х (Choose one) OH (Choose one) OCH3 (Choose one) OH (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forward
- Assign R or S to all the chiral centers in each compound drawn below porat bg 9 Br Brarrow_forwarddescrive the energy levels of an atom and howan electron moces between themarrow_forwardRank each set of substituents using the Cahn-Ingold-Perlog sequence rules (priority) by numbering the highest priority substituent 1.arrow_forward
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