a) Interpretation: The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided. Concept introduction: The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. To identify: The products formed in the reaction given and to provide the mechanism of the reaction.

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Answer 1

Question

Chapter 19.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

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Answer 2

Question

Chapter 19.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Expert Solution & Answer

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Answer 3

Question

Chapter 19.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 19.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Expert Solution & Answer

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See solution

Answer 5

Chapter 19.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 6

Chapter 19.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 7

Chapter 19.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 8

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 9

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 10

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 11

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 19.1 - Prob. 1P Ch. 19.1 - Draw structures corresponding to the following...Ch. 19.2 - Prob. 3P Ch. 19.2 - How would you carry out the following reactions?...Ch. 19.4 - Treatment of an aldehyde or ketone with cyanide...Ch. 19.4 - p-Nitrobenzaldehyde is more reactive toward...Ch. 19.5 - Prob. 7P Ch. 19.5 - The oxygen in water is primarily (99.8) 16O, but...Ch. 19.6 - Prob. 9P Ch. 19.8 - Show the products you would obtain by...

Solution Summary: The author explains the mechanism of the electrophilic substitution reaction, which is an example for Friedal-Crafts acylation reaction.

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Chapter 19 Solutions