Pearson eText Organic Chemistry -- Instant Access (Pearson+)
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
8th Edition
ISBN: 9780135213711
Author: Paula Bruice
Publisher: PEARSON+
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Chapter 19.7, Problem 14P
Interpretation Introduction

Interpretation:

The major product of the given reaction has to be given.

Concept Introduction:

Imidazoles are the aromatic compounds and also the heterocyclic ring of histidine. It exists in both protonated and non-protonated form at pH=7.4. Aromatic compounds such as benzene which is having closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring.

There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
Q: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCC
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Chapter 19 Solutions

Pearson eText Organic Chemistry -- Instant Access (Pearson+)

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