EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 19.6, Problem 17CC

(a)

Interpretation Introduction

Interpretation:

The given reagents used to accomplish the target products (major product) transformation should be draw and identified.

Concept Introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons

Oxime –an oxime is a chemical compound belonging to the imines with the general formula (R1R2C=NOH) . Where R1 represent and organic side chain and R2 represent hydrogen.

Hydrazine is an inorganic material or compound with the chemical formula (NH2NH2) It is a color less flammable liquid with an ammonia-like odour.

Hydrazine is highly toxic and dangerously unstable.

Hydrazine is mainly a foaming agent in preparing polymer foams.

H2SO4 -It’s an oxidizing agent, and popularly known as king of chemicals.

Reagent –It’s a substance or compound added to a system to cause a chemical reaction.

Reactant-It’s a special substance consumed in the course of a chemical reaction to give corresponding product. Reactant always represent in left side and the product must be situated in right side of the reaction.

(b)

Interpretation Introduction

Interpretation:

The given reagents used to accomplish the target products (major product) transformation should be draw and identified.

Concept Introduction:

Oxime –an oxime is a chemical compound belonging to the imines with the general formula (R1R2C=NOH) . Where R1 represent and organic side chain and R2 represent hydrogen.

Hydrazine is an inorganic material or compound with the chemical formula (NH2NH2) It is a color less flammable liquid with an ammonia-like odour.

Hydrazine is highly toxic and dangerously unstable.

Hydrazine is mainly a foaming agent in preparing polymer foams.

H2SO4 -It’s an oxidizing agent, and popularly known as king of chemicals.

Reagent –It’s a substance or compound added to a system to cause a chemical reaction.

Reactant-It’s a special substance consumed in the course of a chemical reaction to give corresponding product. Reactant always represent in left side and the product  must be situated in right side of the reaction.

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1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.
Give the product of the bimolecular elimination from each of the isomeric halogenated compounds. Reaction A Reaction B. КОВ CH₂ HotBu +B+ ко HOIBU +Br+ Templates More QQQ Select Cv Templates More Cras QQQ One of these compounds undergoes elimination 50x faster than the other. Which one and why? Reaction A because the conformation needed for elimination places the phenyl groups and to each other Reaction A because the conformation needed for elimination places the phenyl groups gauche to each other. ◇ Reaction B because the conformation needed for elimination places the phenyl groups gach to each other. Reaction B because the conformation needed for elimination places the phenyl groups anti to each other.
Five isomeric alkenes. A through each undergo catalytic hydrogenation to give 2-methylpentane The IR spectra of these five alkenes have the key absorptions (in cm Compound Compound A –912. (§), 994 (5), 1643 (%), 3077 (1) Compound B 833 (3), 1667 (W), 3050 (weak shoulder on C-Habsorption) Compound C Compound D) –714 (5), 1665 (w), 3010 (m) 885 (3), 1650 (m), 3086 (m) 967 (5), no aharption 1600 to 1700, 3040 (m) Compound K Match each compound to the data presented. Compound A Compound B Compound C Compound D Compound
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