
General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
5th Edition
ISBN: 9780321967466
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 19.4, Problem 19.30QAP
Interpretation Introduction
Interpretation:
Explain the bonding in between amino acids of a polypeptide chain in an helix.
Concept introduction:
Proteins are macromolecules obtained by repetitive combination of amino acids. They exhibit four level of structures viz. Primary, secondary, tertiary, and quaternary.
The two kinds of secondary structures are:
a) helix
b) sheet
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Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 85.0899.
Exact Masses of the Most Abundant Isotope of
Selected Elements
Isotope Natural abundance (%) Exact mass
1H
99.985
1.008
12C
98.90
12.000
14N
99.63
14.003
160
99.76
15.995
Molecular formula
(In the order CHNO, with no subscripts)
Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the
drawing window.
Data selected from the NIST
WebBook,
https://webbook.nist.gov/chemistry/
m/z
Relative intensity
59
3.0
58
64
43
100
15
23
• You do not have to consider stereochemistry.
•You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw one.
+
n[]
85
//
?
CH4
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Next
Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M* = 128.0632.
Exact Masses of the Most Abundant Isotope of
Selected Elements
Isotope Natural abundance (%) Exact mass
1H
99.985
12C
98.90
14N
99.63
160
99.76
Molecular formula
1.008
12.000
14.003
15.995
(In the order CHNO, with no subscripts)
Chapter 19 Solutions
General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
Ch. 19.1 - Prob. 19.1QAPCh. 19.1 - Prob. 19.2QAPCh. 19.1 - Prob. 19.3QAPCh. 19.1 - Prob. 19.4QAPCh. 19.1 - Prob. 19.5QAPCh. 19.1 - Classify each of the amino acids in problem 19.4...Ch. 19.1 - Prob. 19.7QAPCh. 19.1 - Prob. 19.8QAPCh. 19.1 - Draw the Fischer projection for each of the...Ch. 19.1 - Prob. 19.10QAP
Ch. 19.1 - Prob. 19.11QAPCh. 19.1 - Prob. 19.12QAPCh. 19.2 - Prob. 19.13QAPCh. 19.2 - Draw the zwitterion for each of the following...Ch. 19.2 - Prob. 19.15QAPCh. 19.2 - Draw the zwitterion for each of the following...Ch. 19.2 - Prob. 19.17QAPCh. 19.2 - Prob. 19.18QAPCh. 19.3 - Draw the structure for each of the following...Ch. 19.3 - Draw the structure for each of the following...Ch. 19.3 - Prob. 19.21QAPCh. 19.3 - Prob. 19.22QAPCh. 19.3 - Prob. 19.23QAPCh. 19.3 - Peptides from sweet potato with antioxidant...Ch. 19.4 - Prob. 19.25QAPCh. 19.4 - Prob. 19.26QAPCh. 19.4 - Prob. 19.27QAPCh. 19.4 - Prob. 19.28QAPCh. 19.4 - Prob. 19.29QAPCh. 19.4 - Prob. 19.30QAPCh. 19.4 - Prob. 19.31QAPCh. 19.4 - Prob. 19.32QAPCh. 19.4 - Prob. 19.33QAPCh. 19.4 - Prob. 19.34QAPCh. 19.5 - Prob. 19.35QAPCh. 19.5 - Prob. 19.36QAPCh. 19.5 - Prob. 19.37QAPCh. 19.5 - Prob. 19.38QAPCh. 19.5 - Prob. 19.39QAPCh. 19.5 - Prob. 19.40QAPCh. 19.6 - What products would result from the complete...Ch. 19.6 - Prob. 19.42QAPCh. 19.6 - What dipeptides could be produced from the partial...Ch. 19.6 - Prob. 19.44QAPCh. 19.6 - What structural level of a protein is affected by...Ch. 19.6 - Prob. 19.46QAPCh. 19.6 - Prob. 19.47QAPCh. 19.6 - Indicate the changes in the secondary and tertiary...Ch. 19.6 - Prob. 19.49QAPCh. 19.6 - Prob. 19.50QAPCh. 19.6 - 19.51 What is the difference between the secondary...Ch. 19.6 - Prob. 19.52QAPCh. 19.6 - Prob. 19.53QAPCh. 19.6 - Prob. 19.54QAPCh. 19 - Prob. 19.55UTCCh. 19 - Prob. 19.56UTCCh. 19 - Prob. 19.57UTCCh. 19 - Prob. 19.58UTCCh. 19 - Prob. 19.59UTCCh. 19 - Each of three peptides contains one glycine...Ch. 19 - Prob. 19.61UTCCh. 19 - Prob. 19.62UTCCh. 19 - Prob. 19.63AQAPCh. 19 - Prob. 19.64AQAPCh. 19 - Prob. 19.65AQAPCh. 19 - Prob. 19.66AQAPCh. 19 - Prob. 19.67AQAPCh. 19 - Prob. 19.68AQAPCh. 19 - Wou4d you expect a polypeptide with a high content...Ch. 19 - Prob. 19.70AQAPCh. 19 - Prob. 19.71AQAPCh. 19 - Prob. 19.72AQAPCh. 19 - Prob. 19.73AQAPCh. 19 - Prob. 19.74AQAPCh. 19 - Prob. 19.75AQAPCh. 19 - Prob. 19.76AQAPCh. 19 - Prob. 19.77AQAPCh. 19 - Prob. 19.78AQAPCh. 19 - Indicate the overall charge of each amino acid at...Ch. 19 - Prob. 19.80CQCh. 19 - Prob. 19.81CQCh. 19 - Prob. 19.82CQ
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Biomolecules - Protein - Amino acids; Author: Tutorials Point (India) Ltd.;https://www.youtube.com/watch?v=ySNVPDHJ0ek;License: Standard YouTube License, CC-BY