9th Edition

ISBN: 9780321971371

Author: Leroy G. Wade, Jan W. Simek

Publisher: PEARSON

Concept explainers

Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and…

Epoxides

Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic…

Williamson Ether Synthesis

An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction…

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Textbook Question

Chapter 19.20B, Problem 19.30P

Show how you would accomplish the following synthetic conversions.

a. benzyl bromide → benzylamine
b. 1-bromo-2-phenylethane → 3-phenylpropan-1-amine
c. pentanoic acid → pentan-1-amine
d. pentanoic acid → hexan-1-amine
e. (R)-2-bromobutane → (S)-butan-2-amine
f. (R)-2-bromobutane → (S)-2-methylbutan-1-amine
g. hexan-2-one → 1-amino-2-methylhexan-2-ol

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Chapter 19.20A, Problem 19.29P

Chapter 19.20C, Problem 19.31P

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Chapter 19 Solutions

Organic Chemistry (9th Edition)

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

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