The synthesis of the given amine from the indicated starting material by reductive amination. Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described. Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines . Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Question

Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate

Answer 1

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate

Using the table of Reactants and Products provided provide the correct letter that corresponds with the Carboxylic acid that is formed in the reaction below. 6 M NaOH Acid-workup WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES A) Pool of Reagents for Part B CI B) OH C) E) CI J) racemic F) K) OH N) OH P) G) OH D) HO H) L) M) HO Q) R) CI A

In the table below, the exact chemical structures for Methyl salicylate can be represented by the letter WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES CI B) A) E) Cl racemic F) J) CI K) N) OH P) Pool of Reagents for Part B OH OH G) L) OH D) HO H) M) HO Q) R) CI

Answer 2

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 3

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 4

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 5

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 6

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 7

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 8

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 9

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 10

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 11

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 12

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 13

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 14

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 15

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 16

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 17

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 18

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Answer 19

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Answer 29

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author describes the synthesis of the given amine from the indicated starting material by reductive amination.

Chapter 19 Solutions