The synthesis of the given amine from the indicated starting material by reductive amination. Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described. Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines . Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Question

Is nucleophilic acyl substitution an SN1 or SN2 reaction?

Answer 1

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Is nucleophilic acyl substitution an SN1 or SN2 reaction?

Draw product A, indicating what type of reaction occurs. NH2 F3C CF3 NH OMe NH2-NH2, ACOH A

Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Answer 2

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 3

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 4

Question

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 5

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 6

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 7

Chapter 19.18, Problem 19.26P

(a)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 8

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 9

(b)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 10

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 11

(c)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 12

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 13

(d)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 14

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 15

(e)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 16

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 17

(f)

Interpretation Introduction

To describe: The synthesis of the given amine from the indicated starting material by reductive amination.

Interpretation: The synthesis of the given amine from the indicated starting material by reductive amination is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 18

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Answer 19

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Answer 29

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author describes the synthesis of the given amine from the indicated starting material by reductive amination.

Chapter 19 Solutions