
Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Chapter 19, Problem 8QAP
Interpretation Introduction
Interpretation:
Interpret the change in
Concept Introduction:
The decaying of an atom takes place by three type of decay such as alpha decay, beta decay, gama decay.
In alpha decay, an alpha particle with mass 4m and electron 2e removed from nuclide while in beta decay two type of decay are possible beta (+) and beta (-). In gamma decay, nuclide will remain same to the original one.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 19 Solutions
Introductory Chemistry: A Foundation
Ch. 19.1 - Prob. 1CTCh. 19.1 - Prob. 19.1SCCh. 19.1 - Prob. 19.2SCCh. 19.3 - Exercise19.3Watches with numerals that glow in the...Ch. 19.8 - Prob. 1CTCh. 19 - Prob. 1ALQCh. 19 - Prob. 2ALQCh. 19 - Prob. 3ALQCh. 19 - Prob. 4ALQCh. 19 - Prob. 5ALQ
Ch. 19 - Prob. 6ALQCh. 19 - Prob. 7ALQCh. 19 - Prob. 8ALQCh. 19 - Prob. 9ALQCh. 19 - Prob. 10ALQCh. 19 - Prob. 1QAPCh. 19 - Prob. 2QAPCh. 19 - Prob. 3QAPCh. 19 - Prob. 4QAPCh. 19 - Prob. 5QAPCh. 19 - Prob. 6QAPCh. 19 - Prob. 7QAPCh. 19 - Prob. 8QAPCh. 19 - Prob. 9QAPCh. 19 - Prob. 10QAPCh. 19 - Prob. 11QAPCh. 19 - Prob. 12QAPCh. 19 - Prob. 13QAPCh. 19 - Prob. 14QAPCh. 19 - Prob. 15QAPCh. 19 - Prob. 16QAPCh. 19 - Prob. 17QAPCh. 19 - Prob. 18QAPCh. 19 - Prob. 19QAPCh. 19 - Prob. 20QAPCh. 19 - Prob. 21QAPCh. 19 - Prob. 22QAPCh. 19 - Prob. 23QAPCh. 19 - Prob. 24QAPCh. 19 - Prob. 25QAPCh. 19 - Prob. 26QAPCh. 19 - Prob. 27QAPCh. 19 - Prob. 28QAPCh. 19 - Prob. 29QAPCh. 19 - Prob. 30QAPCh. 19 - Prob. 31QAPCh. 19 - Prob. 32QAPCh. 19 - Prob. 33QAPCh. 19 - Prob. 34QAPCh. 19 - Prob. 35QAPCh. 19 - Prob. 36QAPCh. 19 - Prob. 37QAPCh. 19 - Prob. 38QAPCh. 19 - Prob. 39QAPCh. 19 - Prob. 40QAPCh. 19 - Prob. 41QAPCh. 19 - Prob. 42QAPCh. 19 - Prob. 43QAPCh. 19 - Prob. 44QAPCh. 19 - Prob. 45QAPCh. 19 - Prob. 46QAPCh. 19 - Prob. 47QAPCh. 19 - Prob. 48QAPCh. 19 - . How do the forces that hold an atomic nucleus...Ch. 19 - Prob. 50QAPCh. 19 - Prob. 51QAPCh. 19 - Prob. 52QAPCh. 19 - Prob. 53QAPCh. 19 - Prob. 54QAPCh. 19 - Prob. 55QAPCh. 19 - Prob. 56QAPCh. 19 - Prob. 57QAPCh. 19 - Prob. 58QAPCh. 19 - Prob. 59QAPCh. 19 - Prob. 60QAPCh. 19 - Prob. 61QAPCh. 19 - Prob. 62QAPCh. 19 - Prob. 63QAPCh. 19 - Prob. 64QAPCh. 19 - Prob. 65QAPCh. 19 - Prob. 66QAPCh. 19 - Prob. 67QAPCh. 19 - Prob. 68QAPCh. 19 - Prob. 69APCh. 19 - Prob. 70APCh. 19 - Prob. 71APCh. 19 - Prob. 72APCh. 19 - Prob. 73APCh. 19 - Prob. 74APCh. 19 - Prob. 75APCh. 19 - Prob. 76APCh. 19 - Prob. 77APCh. 19 - Prob. 78APCh. 19 - Prob. 79APCh. 19 - . The elements with atomic numbers of 93 or...Ch. 19 - Prob. 81APCh. 19 - Prob. 82APCh. 19 - Prob. 83APCh. 19 - Prob. 84APCh. 19 - Prob. 85APCh. 19 - Prob. 86APCh. 19 - Prob. 87APCh. 19 - Prob. 88APCh. 19 - Prob. 89APCh. 19 - Prob. 90APCh. 19 - Prob. 91APCh. 19 - Prob. 92APCh. 19 - Prob. 93APCh. 19 - Prob. 94APCh. 19 - . The element zinc in nature consists of five...Ch. 19 - . Aluminum exists in several isotopic forms,...Ch. 19 - Prob. 97APCh. 19 - Prob. 98APCh. 19 - Prob. 99APCh. 19 - Prob. 100APCh. 19 - Prob. 101APCh. 19 - Prob. 102APCh. 19 - Prob. 103APCh. 19 - Prob. 104CPCh. 19 - Prob. 105CPCh. 19 - Prob. 106CPCh. 19 - Prob. 107CP
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