Introductory Chemistry: A Foundation
Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 19, Problem 43QAP
Interpretation Introduction

Interpretation:

Interpret dating of archaeological artefact using carbon -14.

Concept Introduction:

Radiocarbon dating is the method of indentifying the age of object which contains organic matter. This property uses the properties of radiocarbon. This technique work by measuring the content of carbon-14 present in matter and thus the age can be determined.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

Chapter 19 Solutions

Introductory Chemistry: A Foundation

Ch. 19.1 - Prob. 1CTCh. 19.1 - Prob. 19.1SCCh. 19.1 - Prob. 19.2SCCh. 19.3 - Exercise19.3Watches with numerals that glow in the...Ch. 19.8 - Prob. 1CTCh. 19 - Prob. 1ALQCh. 19 - Prob. 2ALQCh. 19 - Prob. 3ALQCh. 19 - Prob. 4ALQCh. 19 - Prob. 5ALQ
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