INTRO.TO GENERAL,ORGAN...-OWLV2 ACCESS
INTRO.TO GENERAL,ORGAN...-OWLV2 ACCESS
12th Edition
ISBN: 9781337915977
Author: Bettelheim
Publisher: CENGAGE L
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Chapter 19, Problem 59P
Interpretation Introduction

Interpretation:

The relationship of Laetrile with carbohydrates should be explained. The presence of cyanide group in the structure with connection to the dangers associated with its compound should be explained.

Concept introduction:

Laetrile is the compound which has been utilized as the treatment for the cancer patients. It has another name known as amygdalin. Amygdalin is the bitten compound which is basically present in the fruit pits like, lima beans, raw nuts, apricots, sorghum and clover. It creates hydrogen cyanide i.e. HCN that is altered into cyanide which it is taken in the body.

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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)!

Chapter 19 Solutions

INTRO.TO GENERAL,ORGAN...-OWLV2 ACCESS

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