Chapter 19, Problem 55E

(a)

Interpretation Introduction

Interpretation: The d-orbital splitting diagrams for octahedral complex ion of ${\text{Fe}}^{\text{2+}}$ of high spin and low spin complex needs to be drawn.

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion.

On the basis of energy and degeneracy, the d-orbital can be classified as ${\text{t}}_{\text{2g}}$ and ${\text{e}}_{\text{g}}$ orbitals. The electrons will fill according to their energy levels.

(b)

Interpretation Introduction

Interpretation: The d-orbital splitting diagrams for octahedral complex ion of ${\text{Fe}}^{\text{3+}}$ of high spin complex needs to be drawn.

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion.

On the basis of energy and degeneracy, the d-orbital can be classified as ${\text{t}}_{\text{2g}}$ and ${\text{e}}_{\text{g}}$ orbitals. The electrons will fill according to their energy levels.

(c)

Interpretation Introduction

Interpretation: The d-orbital splitting diagrams for octahedral complex ion of ${\text{Ni}}^{\text{2+}}$ of high spin complex needs to be drawn.

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion.

On the basis of energy and degeneracy, the d-orbital can be classified as ${\text{t}}_{\text{2g}}$ and ${\text{e}}_{\text{g}}$ orbitals. The electrons will fill according to their energy levels.

(d)

Interpretation Introduction

Interpretation: The d-orbital splitting diagrams for octahedral complex ion of ${\text{Zn}}^{\text{2+}}$ of high spin complex needs to be drawn.

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion.

On the basis of energy and degeneracy, the d-orbital can be classified as ${\text{t}}_{\text{2g}}$ and ${\text{e}}_{\text{g}}$ orbitals. The electrons will fill according to their energy levels.

(e)

Interpretation Introduction

Interpretation: The d-orbital splitting diagrams for octahedral complex ion of ${\text{Co}}^{\text{2+}}$ of high spin and low spin complex needs to be drawn.

Concept Introduction:

Crystal field theory is the theory given to explain the bonding in the coordination complexes. As ligand approaches towards the metal ion, the d-orbital of metal ion divide according to the energy of metal ion.

On the basis of energy and degeneracy, the d-orbital can be classified as ${\text{t}}_{\text{2g}}$ and ${\text{e}}_{\text{g}}$ orbitals. The electrons will fill according to their energy levels.