Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 19, Problem 53E
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Pheromone G of the maize stalk borer, chilo partelus, can be synthesized based on the partial scheme shown below. Complete the scheme by identifying the structures of the intermediate compounds A, B, C, D, E, F and pheromone G. Indicate stereochemistry where relevant
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Chapter 19 Solutions
Chemistry
Ch. 19 - Prob. 1RQCh. 19 - Prob. 2RQCh. 19 - Prob. 3RQCh. 19 - Prob. 4RQCh. 19 - Prob. 5RQCh. 19 - Prob. 6RQCh. 19 - Prob. 7RQCh. 19 - Prob. 8RQCh. 19 - Prob. 9RQCh. 19 - Prob. 10RQ
Ch. 19 - Prob. 1QCh. 19 - Prob. 3QCh. 19 - Prob. 4QCh. 19 - Prob. 5QCh. 19 - Prob. 6QCh. 19 - Prob. 7QCh. 19 - Prob. 8QCh. 19 - Prob. 9QCh. 19 - Prob. 10QCh. 19 - Prob. 11QCh. 19 - Prob. 12QCh. 19 - Prob. 13QCh. 19 - Prob. 14QCh. 19 - Prob. 15ECh. 19 - Prob. 16ECh. 19 - Prob. 17ECh. 19 - Prob. 18ECh. 19 - Prob. 19ECh. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 22ECh. 19 - Prob. 23ECh. 19 - Prob. 24ECh. 19 - Prob. 27ECh. 19 - Prob. 28ECh. 19 - Prob. 29ECh. 19 - Prob. 30ECh. 19 - Prob. 32ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - Prob. 38ECh. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Prob. 41ECh. 19 - Prob. 42ECh. 19 - Prob. 43ECh. 19 - Prob. 44ECh. 19 - Prob. 45ECh. 19 - Prob. 46ECh. 19 - Prob. 47ECh. 19 - Prob. 48ECh. 19 - Prob. 49ECh. 19 - Prob. 50ECh. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Prob. 54ECh. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - Prob. 57ECh. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Prob. 60ECh. 19 - Prob. 61ECh. 19 - Prob. 62ECh. 19 - Prob. 63ECh. 19 - Prob. 64ECh. 19 - Prob. 65AECh. 19 - Prob. 66AECh. 19 - Prob. 67AECh. 19 - Prob. 68AECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73AECh. 19 - Prob. 74AECh. 19 - Prob. 75AECh. 19 - Prob. 76AECh. 19 - Prob. 77AECh. 19 - Prob. 78AECh. 19 - Prob. 79AECh. 19 - Prob. 80AECh. 19 - Prob. 81CWPCh. 19 - Prob. 82CWPCh. 19 - Prob. 83CWPCh. 19 - Prob. 84CWPCh. 19 - Prob. 85CWPCh. 19 - Prob. 86CWPCh. 19 - Prob. 87CPCh. 19 - Prob. 88CPCh. 19 - Prob. 89CPCh. 19 - Prob. 90CPCh. 19 - Prob. 91CPCh. 19 - Prob. 92CPCh. 19 - Prob. 93CPCh. 19 - Prob. 94CPCh. 19 - Prob. 95IPCh. 19 - Prob. 96IP
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- Complete the following reaction by identifying the principle organic product of the reactionarrow_forwardDenote the dipole for the indicated bonds in the following molecules. ✓ H3C CH3 B F-CCl3 Br-Cl H3C —Si(CH3)3 CH3 OH HO HO H HO OH vitamin Carrow_forward(a) What is the hybridization of the carbon in the methyl cation (CH3*) and in the methyl anion (CH3)? (b) What is the approximate H-C-H bond angle in the methyl cation and in the methyl anion?arrow_forward
- 10:16 ☑ Vo)) Vo) 4G LTE 76% Complete the following reaction by identifying the principle organic product of the reaction. HO OH ↑ CH2N2 OH ? ○ A. 01 N₂H2C OH ОН B. HO OCH3 OH ○ C. HO OH ŎCH₂N2 ○ D. H3CO OH он Quiz navigation 1 2 3 4 5 11 12 Next page 10 6 7 8 9 10arrow_forwardWhich one of the following statements explain why protecting groups are referred to as “a necessary evil in organic synthesis”? Question 12Select one or more: A. They increase the length and cost of the synthesis B. Every synthesis employs protecting groups C. Protecting group have no role to play in a synthesis D. They minimize the formation of side productsarrow_forwardWhich of the following attributes is a key advantage of the chiral auxiliary approach over the chiral pool approach in asymmetric synthesis? Question 10Select one: A. Chiral auxiliaries are cheaper than chiral pool substrates B. Chiral auxiliary can be recovered and recycled unlike chiral pool substrates. C. The use of chiral auxiliaries provide enantiopure products, while chiral pool reactions are only enantioselective D. The chiral auxiliaries are naturally occurring and do not require synthesisarrow_forward
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- Determine whether the following reaction is an example of a nucleophilic substitution reaction: H NO2 H+ NO 2 + Molecule A Molecule B Is this a nucleophilic substitution reaction? If this is a nucleophilic substitution reaction, answer the remaining questions in this table. What word or two-word phrase is used to describe the role Molecule A plays in this reaction? What word or two-word phrase is used to describe the role Molecule B plays in this reaction? Use a 6 + symbol to label the electrophilic carbon that is attacked during the substitution. Highlight the leaving group on the appropriate reactant. O Yes ○ No ☐ 0 dx 000 HE ?arrow_forwardDraw the major organic product of the Bronsted acid-base reaction. Include all lone pairs and charges as appropriate. Ignore any counterions. :0: NaOH Harrow_forward5. Calculate the total amount of heat transferred as 50 g of wat Specific heat H₂O (g) 2.00 J/g°C -10 °C. Specific heat H₂O (1) Specific heat H₂O (s) 4.18 J/g°C 2.11 J/g°C Heat of vaporization 2260 J/g Heat of fusion 334 J/g Melting point 0°C 6. Calculate the total amount of heat transferred as 25 g of water is heated from 50 °C to 100 °C as a gas. Boiling point 100 °Carrow_forward
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