Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 19, Problem 69AE
Interpretation Introduction

Interpretation: The mass percent of carbon in a typical human body and mass percent of 14C in natural carbon is given. The decay events per second in a 180lb person are to be calculated.

Concept introduction: Nuclei of radioactive element decompose in various ways. There are two major categories. One involves a change in mass number of the decaying nucleus while others do not. Types of radioactive processes include α particle production, β particle production, γ ray production, electron capture and many others.

Expert Solution & Answer
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Answer to Problem 69AE

Answer

The decay events per second in a 180lb person is 4.525×103 decays per second_ .

Explanation of Solution

Explanation

To determine: The decay events per second in a 180lb person.

The number of atoms of 14C in 180lb person is 1.18×1015 g atoms_ .

Weight of person is 180lb .

Mass percent of carbon in typical body is 18% .

Therefore, weight of carbon in person’s body =18×180100=32.4 lb

Mass percent of 14C in natural carbon is 1.6×1010% .

Weight of 32.4 lb 14C in natural carbon =1.6×1010×32.4100=5.184×1011 lb

The conversion of lb to g is done as,

1 lb=453.59 g

Therefore, the conversion of 5.184×1011 lb to g is,

5.184×1011 lb=5.184×1011×453.59 g

Molar mass of 14C is 12 g .

Number of atoms of 14C in 12 g=6.023×1023 atoms .

Therefore, number of atoms of 14C in 5.184×1011×453.59 g=6.022×1023×5.184×1011×453.5912=1.18×1015 g atoms_

Explanation

The value of decay constant is 3.835×10-12 seconds-1_ .

The decay constant is calculated by the formula,

λ=0.693t1/2

Where

  • t1/2 is the half life.
  • λ is decay constant.

The half life of 14C is 5730 years .

The conversion of years to days is done as,

1 year=365 days

Therefore, the conversion of 5730 years to days is as follows,

5730 years=5730×365 days=2091450 days

The conversion of days to hours is done as,

1 day=24 hours

Therefore, the conversion of 2091450 days to hours is as follows,

2091450 days=2091450 × 24 hours=50194800 hours

The conversion of hours to seconds is done as,

1 hour=3600 seconds

Therefore, the conversion of 50194800 hours to seconds is as follows,

50194800 hours=50194800×3600 seconds=180701280000 seconds

Substitute the value of half life in the above formula.

λ=0.693180701280000 seconds=3.835×10-12 seconds-1_ .

Therefore the value of decay constant is 3.835×10-12 seconds-1_ .

Explanation

The rate of decay of 14C in the person is 4.525×103 decay per second_ .

The decay events per second is the rate of decay of 14C and it is calculated by the formula,

Rate=λ×Number of atoms of 14C

Substitute the value of λ and number of atoms of 14C in the above equation.

Rate=3.835×1012×1.18×1015=4.525×103 decay per second_

The rate of decay of 14C in the person is 4.525×103 decay per second_ .

Conclusion

Conclusion

The rate of decay of 14C in the person is 4.525×103 decay per second_ .

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Chapter 19 Solutions

Chemistry

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