Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Chapter 19, Problem 44E
Trimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?
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Chapter 19 Solutions
Chemistry Atoms First2e
Ch. 19 - Write the electron configurations far each of the...Ch. 19 - Write the electron con?gurations for each of the...Ch. 19 - Write the electron configurations for each of the...Ch. 19 - Why are the lanthanoid elements not found in...Ch. 19 - Which of the following elements is most likely to...Ch. 19 - Which of the following is the strongest oxidizing...Ch. 19 - Which of the following elements is most likely to...Ch. 19 - The following reactions all occur in a blast...Ch. 19 - Why is the formation of slag useful during the...Ch. 19 - Would you expect an aqueous manganese (VII) oxide...
Ch. 19 - Iron (II) can be oxidized to iron (III) by...Ch. 19 - How many cubic feet of air at a pressure of 760...Ch. 19 - Find the potentials of the following...Ch. 19 - A 2.5624-g sample of a pure solid alkali metal...Ch. 19 - The standard reduction potential for the reaction...Ch. 19 - Predict the products of each of the following...Ch. 19 - Predict the products of each of the following...Ch. 19 - Describe the electrolytic process for refining...Ch. 19 - Predict the products of the following reactions...Ch. 19 - What is the gas produced when iron(II) sulfide is...Ch. 19 - Predict the products of each of the following...Ch. 19 - Balance the following equations by...Ch. 19 - Dilute sodium cyanide solution is slowly dripped...Ch. 19 - Predict which will be more stable, [CrO4]2- or...Ch. 19 - Give the oxidation state of the metal for each of...Ch. 19 - Indicate the coordination number for the central...Ch. 19 - Give the coordination numbers and write the...Ch. 19 - Give the coordination number for each metal ion in...Ch. 19 - Sketch the structures of the following complexes....Ch. 19 - Draw diagrams for any Cis, trans, and optical...Ch. 19 - Name each of the compounds or ions given in...Ch. 19 - Name each of the compounds or ions given in...Ch. 19 - Specify whether the following complexes have...Ch. 19 - Predict whether the carbonate ligand CO32- will...Ch. 19 - Draw the geometric, linkage, and ionization...Ch. 19 - Determine the number of unpaired electrons...Ch. 19 - Draw the Crystal field diagrams for [Fe(NO2)6]4-...Ch. 19 - Give the oxidation state of the metal, number of d...Ch. 19 - The solid anhydrous solid CoCl2 is blue in color....Ch. 19 - Is it possible for a complex of a metal in the...Ch. 19 - How many unpaired electrons are present in each of...Ch. 19 - Explain how the diphosphate ion, [O3P-O-PO3]4-,...Ch. 19 - For complexes of the same metal ion with no change...Ch. 19 - Trimethylphosphine, P(CH3)3, can act as a ligand...Ch. 19 - Would you expect the complex [Co(en)3]Cl3 to have...Ch. 19 - Would you expect the Mg3[Cr(CN)5]2 to be...Ch. 19 - Would you expect salts of the gold(I) ion, Au+, to...Ch. 19 - [CuCl4]2- is green. [Cu(H2O)6]2+ is blue. Which...
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