
Interpretation:
The total pressure after equilibrium is reestablished for the given reaction has to be calculated.

Explanation of Solution
The reaction is given below.
The first set of equilibrium partial pressures are
By substituting these values in the above expression, the value of equilibrium constant can be calculated.
The pressure of
According to Le Chatelier’s principle, the position of the equilibrium will shift towards right in response to the addition of
To determine the new equilibrium conditions, a pressure table can be set up as given below.
Substitute the equilibrium pressures into the equilibrium – constant expression as shown below.
The value
Then,
The total pressure after equilibrium is re-established can be calculated as given below.
As a final check, it can be shown that,
which agrees with
Therefore, the total pressure after equilibrium is re-established is
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Chapter 19 Solutions
General Chemistry
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