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(a)
Interpretation:
The Major organic product of the given reaction is to be determined.
Concept introduction:
The palladium catalyzed reactions are namely Suzuki coupling and Heck coupling which formed new
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Answer to Problem 19.61P
The major product of given Suzuki reaction of
Explanation of Solution
The Suzuki coupling reaction forms a new
Therefore, the overall Suzuki reaction is
Suzuki reaction, involving possible
(b)
Interpretation:
The Major organic product of the given reaction is to be determined.
Concept introduction:
The palladium catalyzed reactions are namely Suzuki coupling and Heck coupling which formed new
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Answer to Problem 19.61P
The major product of the given Suzuki reaction of
Explanation of Solution
The Suzuki coupling reaction forms a new
Therefore, the overall Suzuki reaction is
Suzuki reaction involving possible E/Z isomerism usually proceeds with retention of configuration of C=C double bond.
(c)
Interpretation:
The Major organic product of the given reaction is to be determined.
Concept introduction:
The palladium catalyzed reactions are namely Suzuki coupling and Heck coupling which formed new
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Answer to Problem 19.61P
The major product of given Heck reaction of
Explanation of Solution
In the given Heck reaction, a new
Therefore, the overall Heck reaction is
If the
(d)
Interpretation:
The Major organic product of the given reaction is to be determined.
Concept introduction:
The palladium catalyzed reactions are namely Suzuki coupling and Heck coupling which formed new

Answer to Problem 19.61P
The major product of given Heck reaction of
Explanation of Solution
The
Therefore, the overall Heck reaction is
If the
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Chapter 19 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
- №3 Fill in the below boxes. HN 1. LAH 2. H3O+ NH2arrow_forwardFor the photochemical halogenation reaction below, draw both propagation steps and include the mechanism arrows for each step. H CH ot CH3 CI-CI MM hv of CH H-CI CH3 2nd attempt See Periodic Table See Hint Draw only radical electrons; do not add lone pair electrons. Note that arrows cannot meet in "space," and must end at either bonds or at atoms. 1 i Add the missing curved arrow notation to this propagation step. 20 H ن S F P H CI Br 品arrow_forwardThe radical below can be stabilized by resonance. 4th attempt Draw the resulting resonance structure. DOCEarrow_forward
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