(a) Interpretation: The major organic product for the given reaction is to be drawn. Concept introduction: In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

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Answer 1

Question

Chapter 19, Problem 19.35P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(c)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Interpretation Introduction

(d)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

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Consider the reaction: 2 A (aq) ⇌ B(aq) Given the following KC values and starting with the initial concentration of A = 4.00 M, complete ICE diagram(s)and find the equilibrium concentrations for A and B.A) KC = 4.00B) KC = 200C) KC = 8.00 x10-3

5) Consider the reaction: Cl2 (g) + F2 (g) ⟷ 2 ClF (g) KP=? The partial pressure of 203 kPa for Cl2 and a partial pressure of 405 kPa for F2. Upon reaching equilibrium, thepartial pressure of ClF is 180 kPa. Calculate the equilibrium concentrations and then find the value for KP.

Don't used hand raiting and don't used Ai solution

Answer 2

Question

Chapter 19, Problem 19.35P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(c)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Interpretation Introduction

(d)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

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Answer 3

Question

Chapter 19, Problem 19.35P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(c)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Interpretation Introduction

(d)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

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Answer 4

Question

Chapter 19, Problem 19.35P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(c)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Interpretation Introduction

(d)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

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Answer 5

Chapter 19, Problem 19.35P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Interpretation Introduction

(c)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Interpretation Introduction

(d)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Answer 6

Chapter 19, Problem 19.35P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Answer 7

Chapter 19, Problem 19.35P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In Heck Coupling reaction R from RX can be vinylic or aryl group. The R’ from H-R’ can be a vinylic or aryl group. X can be Cl, Br or I. In essence, R from R-X replaces H from H-R’ If the R-X halide is vinylic, the configuration about the double bond is retained. If H-R’ is vinylic and has an attached substituent at the opposite end of the C=C then R and the substituent will be trans to each other in the product.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The major organic product for the given reaction is to be drawn.

Concept introduction:

In the Suzuki coupling reaction, under basic condition, a vinylic or aryl halide is treated with an organoboron compound and a palladium catalyst. In this reaction, the four steps involved are oxidation addition, substitution, transmetallation, and reductive elimination. The Suzuki reaction is stereospecific. These reactions involving possible E/Z isomerism usually proceed with retention of configuration.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

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Chapter 19 Solutions