(a) Interpretation: A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated. Concept introduction: The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

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Answer 1

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Complete the mechanism

Answer 2

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Answer 3

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Answer 4

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Answer 5

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

Answer 6

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Answer 7

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

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Chapter 19 Solutions