Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
bartleby

Concept explainers

Question
Book Icon
Chapter 18.10, Problem 14P
Interpretation Introduction

Interpretation:

The structures of the aminal and the imine products formed in the given reactions are to be determined.

Concept introduction:

Aldehydes and ketones contain carbonyl (C=O) functional group in their parent chain. They are polar molecules due to the presence of an electronegative oxygen atom that tends to attract the electrons in the double bond closer to itself as compared to the carbon atom.

The oxygen acquires a partial negative charge and creates a partial positive charge on carbon atom. Aldehydes and ketones easily undergo nucleophilic addition reactions in which the nucleophile attacks at the carbonyl carbon atom.

The chemical compounds that consist of a carbon-nitrogen double bond (C=N) in their structure are commonly known as imine.

The nucleophilic addition reaction of an amine to the carbonyl carbon atom results in the formation of hemiaminal intermediate which further on dehydration forms the imine product.

Blurred answer
Students have asked these similar questions
3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)
In the decomposition reaction in solution B → C, only species C absorbs UV radiation, but neither B nor the solvent absorbs. If we call At the absorbance measured at any time, A0 the absorbance at the beginning of the reaction, and A∞ the absorbance at the end of the reaction, which of the expressions is valid? We assume that Beer's law is fulfilled.
> You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: 1. ☑ CI 2. H3O+ O Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. Explanation Check ? DO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility

Chapter 18 Solutions

Organic Chemistry - Standalone book

Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
  • Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305080485
    Author:John E. McMurry
    Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning