Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 18, Problem 54DSP
Interpretation Introduction

Interpretation:

The configuration at the carbon in the product isto be determined.

Concept Introduction:

During the Baeyer Villiger oxidation of ketones, an oxygen atom is inserted between the carbonyl group and one of the carbons attached to it. The product formed is an ester.

Usually, the oxygen atom is inserted between the carbonyl and the larger of the two groups attached to the carbonyl.

The ketone is converted to the conjugate acid of the ester. Further hydrolysis of the conjugate acid forms the ester.

The peroxy acid used is converted to the corresponding carboxylic acid.

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Chapter 18 Solutions

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