Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
6th Edition
ISBN: 9780134983783
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 18.1, Problem 2PP
Interpretation Introduction
Interpretation:
The difference between an aldose and a ketose should be stated.
Concept introduction:
An aldose refers to a monosaccharide having a carbon chain with a carbonyl group attached to the endmost carbon of the structure, which thus leads to the formation of an
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 18 Solutions
Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
Ch. 18.1 - Prob. 1PPCh. 18.1 - Prob. 2PPCh. 18.1 - Prob. 3PPCh. 18.1 - Prob. 4PPCh. 18.1 - Prob. 5PPCh. 18.1 - Prob. 6PPCh. 18.1 - Prob. 7PPCh. 18.1 - Prob. 8PPCh. 18.1 - Prob. 9PPCh. 18.1 - Prob. 10PP
Ch. 18.1 - Prob. 11PPCh. 18.1 - Prob. 12PPCh. 18.2 - Prob. 13PPCh. 18.2 - Prob. 14PPCh. 18.2 - Prob. 15PPCh. 18.2 - Prob. 16PPCh. 18.2 - Prob. 17PPCh. 18.2 - Prob. 18PPCh. 18.2 - Prob. 19PPCh. 18.2 - Prob. 20PPCh. 18.3 - Classify each of the following fatty acids as...Ch. 18.3 - Classify each of the following fatty acids as...Ch. 18.3 - Prob. 23PPCh. 18.3 - Prob. 24PPCh. 18.3 - Prob. 25PPCh. 18.3 - Olive oil is monounsaturated, whereas butter fat...Ch. 18.3 - Prob. 27PPCh. 18.3 - Use condensed structural formulas to write the...Ch. 18.3 - Prob. 29PPCh. 18.3 - Use condensed structural formulas to write the...Ch. 18.3 - Prob. 31PPCh. 18.3 - Prob. 32PPCh. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Prob. 35PPCh. 18.4 - Prob. 36PPCh. 18.4 - Give the name of the amino acid represented by...Ch. 18.4 - Prob. 38PPCh. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Prob. 40PPCh. 18.4 - Prob. 41PPCh. 18.4 - Prob. 42PPCh. 18.4 - Peptides isolated from rapeseed that may lower...Ch. 18.4 - Prob. 44PPCh. 18.5 - Prob. 45PPCh. 18.5 - Prob. 46PPCh. 18.5 - Prob. 47PPCh. 18.5 - Prob. 48PPCh. 18.5 - Prob. 49PPCh. 18.5 - What type of interaction would you expect between...Ch. 18.5 - Prob. 51PPCh. 18.5 - Prob. 52PPCh. 18.6 - Prob. 53PPCh. 18.6 - Match the terms, (1) active site, (2) lock-and-key...Ch. 18.6 - Prob. 55PPCh. 18.6 - Prob. 56PPCh. 18.7 - Prob. 57PPCh. 18.7 - Identify each of the following bases as a...Ch. 18.7 - Prob. 59PPCh. 18.7 - Prob. 60PPCh. 18.7 - Prob. 61PPCh. 18.7 - Prob. 62PPCh. 18.7 - Prob. 63PPCh. 18.7 - Prob. 64PPCh. 18.8 - Prob. 65PPCh. 18.8 - Prob. 66PPCh. 18.8 - Prob. 67PPCh. 18.8 - Prob. 68PPCh. 18.8 - Prob. 69PPCh. 18.8 - Prob. 70PPCh. 18.8 - Prob. 71PPCh. 18.8 - Prob. 72PPCh. 18.8 - Prob. 73PPCh. 18.8 - Prob. 74PPCh. 18 - Prob. 75UTCCh. 18 - Prob. 76UTCCh. 18 - Prob. 77UTCCh. 18 - Prob. 78UTCCh. 18 - Prob. 79UTCCh. 18 - Prob. 80UTCCh. 18 - Prob. 81UTCCh. 18 - Prob. 82UTCCh. 18 - Prob. 83UTCCh. 18 - Prob. 84UTCCh. 18 - Prob. 85UTCCh. 18 - Prob. 86UTCCh. 18 - Prob. 87APPCh. 18 - Prob. 88APPCh. 18 - Prob. 89APPCh. 18 - Prob. 90APPCh. 18 - Prob. 91APPCh. 18 - Prob. 92APPCh. 18 - Prob. 93APPCh. 18 - Prob. 94APPCh. 18 - Prob. 95APPCh. 18 - Prob. 96APPCh. 18 - Prob. 97APPCh. 18 - Prob. 98APPCh. 18 - Prob. 99APPCh. 18 - Prob. 100APPCh. 18 - Prob. 101CPCh. 18 - Prob. 102CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 104CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 106CPCh. 18 - Prob. 107CPCh. 18 - Prob. 108CPCh. 18 - Prob. 109CPCh. 18 - Prob. 110CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 112CPCh. 18 - A compound called butylated hydroxytoluene, or...Ch. 18 - Olive oil contains a high percentage of glyceryl...Ch. 18 - A sink drain can become clogged with solid fat...Ch. 18 - Prob. 44CICh. 18 - Prob. 45CICh. 18 - Prob. 46CI
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