The standard Gibb’s energy, Δ G o for the following reaction is to be calculated. Concept Information: Gibbs free energy is a thermodynamic quantity that can be used to calculate the maximum work done by any thermodynamic system at constant temperature and pressure. It can also be defined as the change in enthalpy of a thermodynamic system, minus the product of the change in entropy of the system and the absolute temperature. It can be represented by the equation, Δ G 0 = Δ H − T Δ S Here, Δ G 0 is the change in Gibbs free energy, Δ H is the change in enthalpy, T is the change in temperature, and Δ S is the change in entropy of the system. Entropy is a thermodynamic quantity that represents the absence of a particular system’s thermal energy for conversion into mechanical work. The entropy of one mole of a substance at a standard temperature of 298 K is known as its standard molar entropy ( S° ) .
The standard Gibb’s energy, Δ G o for the following reaction is to be calculated. Concept Information: Gibbs free energy is a thermodynamic quantity that can be used to calculate the maximum work done by any thermodynamic system at constant temperature and pressure. It can also be defined as the change in enthalpy of a thermodynamic system, minus the product of the change in entropy of the system and the absolute temperature. It can be represented by the equation, Δ G 0 = Δ H − T Δ S Here, Δ G 0 is the change in Gibbs free energy, Δ H is the change in enthalpy, T is the change in temperature, and Δ S is the change in entropy of the system. Entropy is a thermodynamic quantity that represents the absence of a particular system’s thermal energy for conversion into mechanical work. The entropy of one mole of a substance at a standard temperature of 298 K is known as its standard molar entropy ( S° ) .
Solution Summary: The author explains Gibb's free energy, which can be used to calculate the maximum work done by any thermodynamic system at constant temperature and pressure.
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
Chapter 18, Problem 86RQ
Interpretation Introduction
Interpretation:
The standard Gibb’s energy, ΔGo for the following reaction is to be calculated.
Concept Information:
Gibbs free energy is a thermodynamic quantity that can be used to calculate the maximum work done by any thermodynamic system at constant temperature and pressure.
It can also be defined as the change in enthalpy of a thermodynamic system, minus the product of the change in entropy of the system and the absolute temperature.
It can be represented by the equation,
ΔG0=ΔH−TΔS
Here, ΔG0 is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the change in temperature, and ΔS is the change in entropy of the system.
Entropy is a thermodynamic quantity that represents the absence of a particular system’s thermal energy for conversion into mechanical work.
The entropy of one mole of a substance at a standard temperature of 298 K is known as its standard molar entropy (S°).
There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell