7th Edition

ISBN: 9780321803221

Author: Paula Y. Bruice

Publisher: Prentice Hall

Concept explainers

The heterogeneous classes of organic compounds that are not water-soluble but are dissolved in organic solvents that are non-polar in nature are termed lipids. They are a long chain of fatty acids and esters of alcohols. Lipids are generally seen in seve…

Glycerophospholipid

Glycerophospholipid is the most abundantly occuring phospholipids found in the biological membranes. Lipids include a group of organic compounds like fats, hormones, oils, waxes, vitamins etc. They are non-polar molecules and are insoluble in water. Lipi…

Structure Of Camphor

A terpene with the molecular formula of C10H16O is a waxy, white color solid known as camphor. It is flammable. It also possesses a very pungent taste and a strong odor. There are various sources for extracting camphor from natural products such as the …

Glycolipid In Organic Chemistry

Glycolipids are lipids that are an important class of organic compounds in chemistry that have simple to complex applications. They contain carbohydrates, fatty acids, sphingolipids or a glycerol group. In other words, they are the modifications of lipid…

Diterpenoid

The terpenoid class includes diterpenoids, which are chemical compounds with 20 carbon atoms. They are made up of four isoprene units and are derived from geranylgeraniol, a C20 precursor. They have a C20H32 basic structure. These characteristics disting…

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Textbook Question

Chapter 18, Problem 80P

A Cannizzaro reaction is the reaction of an aldehyde that has no α-hydrogens with concentrated aqueous sodium hydroxide. In this reaction, half the aldehyde is convened to a carboxylic acid and the other half is converted to an alcohol. Propose a mechanism for the following Cannizzaro reaction:

Chapter 18, Problem 80P, A Cannizzaro reaction is the reaction of an aldehyde that has no -hydrogens with concentrated

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

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Chapter 18, Problem 79P

Chapter 18, Problem 81P

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Chapter 18 Solutions

Organic Chemistry

Ch. 18.1 - Prob. 1P Ch. 18.1 - Prob. 2P Ch. 18.1 - Prob. 3P Ch. 18.1 - Prob. 4P Ch. 18.1 - PROBLEM 5♦ List the compounds in each of the...Ch. 18.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 18.3 - Draw the enol tautomers for each of the following...Ch. 18.3 - Prob. 8P Ch. 18.4 - Prob. 9P Ch. 18.4 - Prob. 10P

Ch. 18.5 - Show how the following compounds can be prepared...Ch. 18.6 - What compound is formed when a dilute solution of...Ch. 18.7 - Prob. 13P Ch. 18.7 - Prob. 14P Ch. 18.7 - How many stereoisomers are obtained from each of...Ch. 18.7 - Prob. 16P Ch. 18.8 - Prob. 17P Ch. 18.9 - Prob. 18P Ch. 18.9 - Prob. 19P Ch. 18.10 - Prob. 20P Ch. 18.10 - What aldehyde or ketone would be obtained when...Ch. 18.11 - Prob. 22P Ch. 18.12 - Prob. 24P Ch. 18.12 - What two carbonyl compound are required for the...Ch. 18.12 - Propose a mechanism for the following reaction:Ch. 18.13 - Draw the products of the following reactions:Ch. 18.13 - Prob. 28P Ch. 18.13 - Prob. 29P Ch. 18.14 - Prob. 30P Ch. 18.15 - Write the mechanism for the reaction of a...Ch. 18.15 - Prob. 32P Ch. 18.15 - Prob. 33P Ch. 18.15 - Draw the product of the reaction of each of the...Ch. 18.16 - Draw the product obtained by heating each pair of...Ch. 18.16 - Prob. 36P Ch. 18.17 - Prob. 37P Ch. 18.18 - Prob. 38P Ch. 18.18 - Prob. 39P Ch. 18.19 - Prob. 40P Ch. 18.20 - Prob. 42P Ch. 18.21 - Propose a mechanism for the formation of...Ch. 18.21 - Prob. 44P Ch. 18.21 - a. If the biosynthesis of palmitic acid were...Ch. 18.21 - Prob. 46P Ch. 18 - Prob. 47P Ch. 18 - Prob. 48P Ch. 18 - Number the following compounds in order of...Ch. 18 - The 1H NMR chemical shifts of nitromethane,...Ch. 18 - Prob. 51P Ch. 18 - Draw the products of the following reactions: a....Ch. 18 - A racemic mixture of 2-methyl-1-phenyl-1-butanone...Ch. 18 - Prob. 54P Ch. 18 - Prob. 55P Ch. 18 - Prob. 56P Ch. 18 - Prob. 57P Ch. 18 - Identify A-L. (Hint: A shows three singles in its...Ch. 18 - Using cyclopentanone as the reactant, show the...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - Prob. 61P Ch. 18 - Prob. 62P Ch. 18 - Prob. 63P Ch. 18 - The ketone whose 1H NMR spectrum is shown here was...Ch. 18 - Prob. 65P Ch. 18 - Compound A with molecular formula C6H10 has two...Ch. 18 - Indicate how each of the following compounds can...Ch. 18 - Draw the products of the following reactions:Ch. 18 - Prob. 69P Ch. 18 - a. Show how the amino acid alanine can be...Ch. 18 - Prob. 71P Ch. 18 - Show how the following compounds can be...Ch. 18 - Explain why the following bromoketone forms...Ch. 18 - Prob. 74P Ch. 18 - What carbonyl compounds are required to prepare a...Ch. 18 - Prob. 76P Ch. 18 - A carboxylic arid is formed when an -haloketone...Ch. 18 - An , -unsaturated carbonyl compound can be...Ch. 18 - Prob. 79P Ch. 18 - A Cannizzaro reaction is the reaction of an...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - The following reaction is known as the benzoni...Ch. 18 - Prob. 83P Ch. 18 - Prob. 84P Ch. 18 - Prob. 85P Ch. 18 - Prob. 86P Ch. 18 - Propose a mechanism for the following reaction:

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A Cannizzaro reaction is the reaction of an aldehyde that has no α -hydrogens with concentrated aqueous sodium hydroxide. In this reaction, half the aldehyde is convened to a carboxylic acid and the other half is converted to an alcohol. Propose a mechanism for the following Cannizzaro reaction:

Solution Summary: The author explains the mechanism of Cannizzaro reaction. Aldehyde has no alpha hydrogen atom.

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Chapter 18 Solutions