Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 18, Problem 65P

(a)

Interpretation Introduction

Interpretation:

It should be indicated that how the given compound could be synthesized from cyclohexanone and any other necessary reagents.

Concept introduction:

Reagent is a compound which is added to a system to cause a chemical reaction or test if a reaction occurs.

Cyclohexanone is carbonyl compound which gives variety of reactions including reduction, oxidation and nucleophilic addition reaction depending upon the chemical conditions in the reaction medium.

LDA (Lithium Diisopropylamide) is used as a strong base and it has been widely accepted due to its good solubility in non-polar organic solvent.

(b)

Interpretation Introduction

Interpretation:

It should be indicated that how the given compound could be synthesized from cyclohexanone and any other necessary reagents.

Concept introduction:

Reagent is a compound which is added to a system to cause a chemical reaction or test if a reaction occurs.

Cyclohexanone is carbonyl compound which gives variety of reactions including reduction, oxidation and nucleophilic addition reaction depending upon the chemical conditions in the reaction medium.

LDA (Lithium Diisopropylamide) is used as a strong base and it has been widely accepted due to its good solubility in non-polar organic solvent.

(c)

Interpretation Introduction

Interpretation:

It should be indicated that how the given compound could be synthesized from cyclohexanone and any other necessary reagents.

Concept introduction:

Reagent is a compound which is added to a system to cause a chemical reaction or test if a reaction occurs.

Cyclohexanone is carbonyl compound which gives variety of reactions including reduction, oxidation and nucleophilic addition reaction … depending upon the chemical conditions in the reaction medium.

(d)

Interpretation Introduction

Interpretation:

It should be indicated that how the given compound could be synthesized from cyclohexanone and any other necessary reagents.

Concept introduction:

Reagent is a compound which is added to a system to cause a chemical reaction or test if a reaction occurs.

Cyclohexanone is carbonyl compound which gives variety of reactions including reduction, oxidation and nucleophilic addition reaction depending upon the chemical conditions in the reaction medium.

(e)

Interpretation Introduction

Interpretation: It should be indicated that how the given compound could be synthesized from cyclohexanone and any other necessary reagents.

Concept introduction:

Cyclohexanone is carbonyl compound which gives variety of reactions including reduction, oxidation and nucleophilic addition reaction depending upon the chemical conditions in the reaction medium.

Robinson annulation:

In the presence of enough bases, the product of the Michael reaction undergoes a spontaneous intramolecular aldol condensation, usually with dehydration to give a six membered ring-a conjugated cyclohexanone.

Organic Chemistry, Chapter 18, Problem 65P

Reduction can be done using hydrogen (one of the simplest reducing agent) with a metal catalyst.

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Chapter 18 Solutions

Organic Chemistry

Ch. 18.5 - Show how the following compounds can be prepared...Ch. 18.6 - What compound is formed when a dilute solution of...Ch. 18.7 - Prob. 13PCh. 18.7 - Prob. 14PCh. 18.7 - How many stereoisomers are obtained from each of...Ch. 18.7 - Prob. 16PCh. 18.8 - Prob. 17PCh. 18.9 - Prob. 18PCh. 18.9 - Prob. 19PCh. 18.10 - Prob. 20PCh. 18.10 - What aldehyde or ketone would be obtained when...Ch. 18.11 - Prob. 22PCh. 18.12 - Prob. 24PCh. 18.12 - What two carbonyl compound are required for the...Ch. 18.12 - Propose a mechanism for the following reaction:Ch. 18.13 - Draw the products of the following reactions:Ch. 18.13 - Prob. 28PCh. 18.13 - Prob. 29PCh. 18.14 - Prob. 30PCh. 18.15 - Write the mechanism for the reaction of a...Ch. 18.15 - Prob. 32PCh. 18.15 - Prob. 33PCh. 18.15 - Draw the product of the reaction of each of the...Ch. 18.16 - Draw the product obtained by heating each pair of...Ch. 18.16 - Prob. 36PCh. 18.17 - Prob. 37PCh. 18.18 - Prob. 38PCh. 18.18 - Prob. 39PCh. 18.19 - Prob. 40PCh. 18.20 - Prob. 42PCh. 18.21 - Propose a mechanism for the formation of...Ch. 18.21 - Prob. 44PCh. 18.21 - a. If the biosynthesis of palmitic acid were...Ch. 18.21 - Prob. 46PCh. 18 - Prob. 47PCh. 18 - Prob. 48PCh. 18 - Number the following compounds in order of...Ch. 18 - The 1H NMR chemical shifts of nitromethane,...Ch. 18 - Prob. 51PCh. 18 - Draw the products of the following reactions: a....Ch. 18 - A racemic mixture of 2-methyl-1-phenyl-1-butanone...Ch. 18 - Prob. 54PCh. 18 - Prob. 55PCh. 18 - Prob. 56PCh. 18 - Prob. 57PCh. 18 - Identify A-L. (Hint: A shows three singles in its...Ch. 18 - Using cyclopentanone as the reactant, show the...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - Prob. 61PCh. 18 - Prob. 62PCh. 18 - Prob. 63PCh. 18 - The ketone whose 1H NMR spectrum is shown here was...Ch. 18 - Prob. 65PCh. 18 - Compound A with molecular formula C6H10 has two...Ch. 18 - Indicate how each of the following compounds can...Ch. 18 - Draw the products of the following reactions:Ch. 18 - Prob. 69PCh. 18 - a. Show how the amino acid alanine can be...Ch. 18 - Prob. 71PCh. 18 - Show how the following compounds can be...Ch. 18 - Explain why the following bromoketone forms...Ch. 18 - Prob. 74PCh. 18 - What carbonyl compounds are required to prepare a...Ch. 18 - Prob. 76PCh. 18 - A carboxylic arid is formed when an -haloketone...Ch. 18 - An , -unsaturated carbonyl compound can be...Ch. 18 - Prob. 79PCh. 18 - A Cannizzaro reaction is the reaction of an...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - The following reaction is known as the benzoni...Ch. 18 - Prob. 83PCh. 18 - Prob. 84PCh. 18 - Prob. 85PCh. 18 - Prob. 86PCh. 18 - Propose a mechanism for the following reaction:
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