
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 18, Problem 60P
Interpretation Introduction
Interpretation:
The reason to why anisole is more rapidly nitrated as compared to thioanisole under same conditions has to be explained.
Concept Introduction:
Electrophilic substitution reaction in the benzene ring becomes more favorable by increase in the electron density on the benzene ring either by resonance, hyperconjugation or by inductive effect. More is the electron density on benzene ring, faster will be the reaction.
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Identify the mechanism through which the following reaction will proceed and draw the major product.
Part 1 of 2
Br
KOH
EtOH
Through which mechanism will the reaction proceed? Select the single best answer.
E1
E2
neither
Part: 1/2
Part 2 of 2
Draw the major product formed as a result of the reaction.
Click and drag to start drawing a
structure.
X
What is single-point calibration? Provide an example.
Draw the major product formed via an E1 pathway.
Chapter 18 Solutions
Organic Chemistry (8th Edition)
Ch. 18.1 - Draw the structure for each of the following: a....Ch. 18.3 - Why does hydration inactivate FeBr3?Ch. 18.6 - Prob. 4PCh. 18.7 - What is the major product of a Friedel-Crafts...Ch. 18.9 - Describe two ways to prepare each of the following...Ch. 18.10 - Prob. 7PCh. 18.11 - Name the following:Ch. 18.11 - Draw a structure for each of the following: a....Ch. 18.11 - Draw the structure for each of the following: a....Ch. 18.11 - Correct the following incorrect names: a....
Ch. 18.12 - Prob. 14PCh. 18.12 - List the compounds in each set from most reactive...Ch. 18.13 - Prob. 16PCh. 18.13 - What product(s) result from nitration of each of...Ch. 18.13 - Prob. 18PCh. 18.13 - What products are obtained from the reaction of...Ch. 18.15 - Give the products, if any, of each of the...Ch. 18.16 - a. Does a coupling reaction have to be used to...Ch. 18.16 - Show how the following compounds can be...Ch. 18.16 - Prob. 24PCh. 18.17 - What is the major product(s) of each of the...Ch. 18.17 - Prob. 26PCh. 18.18 - Why isn't FeBr3 used as a catalyst in the first...Ch. 18.18 - Prob. 29PCh. 18.18 - Write the sequence of steps required for the...Ch. 18.18 - Show how the following compounds can be...Ch. 18.19 - What product is formed from reaction of...Ch. 18.19 - Prob. 33PCh. 18.19 - Draw the structure of the activated ring and the...Ch. 18.20 - Prob. 35PCh. 18.20 - Prob. 36PCh. 18.20 - Diazomethane can be used to convert a carboxylic...Ch. 18.21 - Prob. 38PCh. 18.21 - Prob. 39PCh. 18.21 - Prob. 40PCh. 18.22 - Prob. 41PCh. 18 - Draw the structure for each of the following: a....Ch. 18 - Name the following:Ch. 18 - Prob. 44PCh. 18 - Prob. 45PCh. 18 - For each of the statements in Column I, choose a...Ch. 18 - What product is obtained from the reaction of...Ch. 18 - Draw the product(s) of each of the following...Ch. 18 - Rank the following substituted anilines from most...Ch. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Show how the following compounds can be...Ch. 18 - Prob. 53PCh. 18 - The compound with the 1H NMR spectrum shown below...Ch. 18 - Rank each group of compounds from most reactive to...Ch. 18 - Prob. 56PCh. 18 - Prob. 57PCh. 18 - For each of the following components, indicate the...Ch. 18 - Prob. 59PCh. 18 - Prob. 60PCh. 18 - Describe two ways to prepare anisole from benzene.Ch. 18 - Prob. 62PCh. 18 - The following tertiary alkyl bromides undergo an...Ch. 18 - An aromatic hydrocarbon with a molecular formula...Ch. 18 - Show how the following compounds can be...Ch. 18 - Use the four compounds shown below to answer the...Ch. 18 - a. Rank the following esters from most reactive to...Ch. 18 - A mixture of 0.10 mol benzene and 0.10 mol...Ch. 18 - Prob. 69PCh. 18 - Prob. 70PCh. 18 - Benzene underwent a Friedel-Crafts acylation...Ch. 18 - Prob. 72PCh. 18 - Prob. 73PCh. 18 - Friedel-Crafts alkylations can be carried out with...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - Prob. 76PCh. 18 - Prob. 77PCh. 18 - a. Describe four ways the following reaction can...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - How can you prepare the following compounds with...Ch. 18 - Describe how naphthalene can he prepared from the...Ch. 18 - Using resonance contributors for the carbocation...Ch. 18 - Prob. 83PCh. 18 - What reagents are required to carry out the...Ch. 18 - Prob. 85PCh. 18 - Prob. 86PCh. 18 - Prob. 87PCh. 18 - Propose a mechanism for each of the following...Ch. 18 - P-Fluoronitrobenzene is more reactive toward...Ch. 18 - When heated with chromic acid, compound A forms...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - How can you distinguish the following compounds...Ch. 18 - Describe how mescaline can be synthesized from...Ch. 18 - Propose a mechanism for the following reaction...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - Describe how 3-methyl-1-phenyl-3-pentanol can he...Ch. 18 - An unknown compound reacts with ethyl chloride and...Ch. 18 - a. Explain why the following reaction leads to the...Ch. 18 - Explain why hydroxide ion catalyzes the reaction...Ch. 18 - Prob. 100PCh. 18 - Prob. 101PCh. 18 - a. How can aspirin be synthesized from benzene? b....Ch. 18 - Prob. 103PCh. 18 - Show how Novocain, a painkiller used frequently by...Ch. 18 - Prob. 105PCh. 18 - Saccharin, an artificial sweetener, is about 300...
Knowledge Booster
Similar questions
- Part 9 of 9 Consider the products for the reaction. Identify the major and minor products. HO Cl The E stereoisomer is the major product and the Z stereoisomer is the minor product ▼ S major product minor productarrow_forwardConsider the reactants below. Answer the following questions about the reaction mechanism and products. HO Clarrow_forwardjulietteyep@gmail.com X YSCU Grades for Juliette L Turner: Orc X 199 A ALEKS - Juliette Turner - Modul X A ALEKS - Juliette Turner - Modul x G butane newman projection - Gox + www-awa.aleks.com/alekscgi/x/Isl.exe/10_u-IgNslkr7j8P3jH-IBxzaplnN4HsoQggFsejpgqKoyrQrB2dKVAN-BcZvcye0LYa6eXZ8d4vVr8Nc1GZqko5mtw-d1MkNcNzzwZsLf2Tu9_V817y?10Bw7QYjlb il Scribbr citation APA SCU email Student Portal | Main Ryker-Learning WCU-PHARM D MySCU YSCU Canvas- SCU Module 4: Homework (Ch 9-10) Question 28 of 30 (1 point) | Question Attempt: 1 of Unlimited H₂SO heat OH The mechanism of this reaction involves two carbocation intermediates, A and B. Part 1 of 2 KHSO 4 rearrangement A heat B H₂O 2 OH Draw the structure of A. Check Search #t m Save For Later Juliet Submit Assignm 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forward
- The electrons flow from the electron-rich atoms of the nucleophile to the electrons poor atoms of the alkyl halide. Identify the electron rich in the nucleophile. Enter the element symbol only, do not include any changes.arrow_forwardHello, I am doing a court case analysis in my Analytical Chemistry course. The case is about a dog napping and my role is prosecution of the defendant. I am tasked in the Area of Expertise in Neutron Activation and Isotopic Analysis. Attached is the following case study reading of my area of expertise! The landscaping stone was not particularly distinctive in its decoration but matched both the color and pattern of the Fluential’s landscaping stone as well as the stone in the back of the recovered vehicle. Further analysis of the stone was done using a technique called instrumental neutron activation analysis. (Proceed to Neutron Activation data) Photo Notes: Landscaping stone recovered in vehicle. Stone at Fluential’s home is similar inappearance. Finally, the white paint on the brick was analyzed using stable isotope analysis. The brick recovered at the scene had smeared white paint on it. A couple of pieces of brick in the back of the car had white paint on them. They…arrow_forwardCite the stability criteria of an enamine..arrow_forward
- What would you expect to be the major product obtained from the following reaction? Please explain what is happening here. Provide a detailed explanation and a drawing showing how the reaction occurs. The correct answer to this question is V.arrow_forwardPlease answer the question for the reactions, thank youarrow_forwardWhat is the product of the following reaction? Please include a detailed explanation of what is happening in this question. Include a drawing showing how the reagent is reacting with the catalyst to produce the correct product. The correct answer is IV.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning


Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning

Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning