ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
10th Edition
ISBN: 9781260001099
Author: Carey
Publisher: MCG
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Chapter 18, Problem 57DSP
Interpretation Introduction

Interpretation:

The identity of the compound X in the given reaction isto be determined.

Concept Introduction:

During the Baeyer Villiger oxidation of ketones, an oxygen atom is inserted between the carbonyl group and one of the carbons attached to it. The product formed is an ester.

Usually, the oxygen atom is inserted between the carbonyl and the larger of the two groups attached to the carbonyl.

The ketone is converted to the conjugate acid of the ester. Further hydrolysis of the conjugated acid forms the ester.

The peroxy acid used is converted to the corresponding carboxylic acid.

The alkyl group migrates with retention of configuration.

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Chapter 18 Solutions

ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.

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