(a) Interpretation: The products formed when ethyl benzoate is treated with the following set of reagents should be determined. H 2 O, NaOH, heat. Concept Introduction: Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Question

bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 4P

Interpretation Introduction

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Interpretation Introduction

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

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bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

PROBLEM 4 Solved Show how 1-butanol can be converted into the following compounds: a. PROBLEM 5+ b. d. -C= N

Which alkene is the major product of this dehydration? OH H2SO4 heat

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 4P

Interpretation Introduction

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Interpretation Introduction

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 4P

Interpretation Introduction

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Interpretation Introduction

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18, Problem 4P

Interpretation Introduction

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Interpretation Introduction

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

Expert Solution & Answer

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Answer 5

Chapter 18, Problem 4P

Interpretation Introduction

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Interpretation Introduction

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

Answer 6

Chapter 18, Problem 4P

Interpretation Introduction

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Answer 7

Chapter 18, Problem 4P

Interpretation Introduction

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Answer 8

Interpretation Introduction

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

Answer 10

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Answer 11

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Ch. 18.1 - Prob. 18.1QC Ch. 18.4 - Problem 19-2 Complete the equation for each...Ch. 18.4 - Prob. 18.3QC Ch. 18 - Prob. 1P Ch. 18 - Write the IUPAC name for each compound.Ch. 18 - Prob. 3P Ch. 18 - Prob. 4P Ch. 18 - Prob. 5P Ch. 18 - Prob. 6P Ch. 18 - 0 Complete the equations for these reactions.

(a) Interpretation: The products formed when ethyl benzoate is treated with the following set of reagents should be determined. H 2 O, NaOH, heat. Concept Introduction: Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Solution Summary: The author explains that the products formed when ethyl benzoate is treated with the following set of reagents should be determined.

(a)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, NaOH, heat.

Concept Introduction:

Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

(b)

Interpretation:

The products formed when ethyl benzoate is treated with the following set of reagents should be determined.

H₂ O, HCl, heat.

Concept Introduction:

Acid hydrolysis of an ester produces carboxylic acid and alcohol.

Chapter 18 Solutions

(a) Interpretation: The products formed when ethyl benzoate is treated with the following set of reagents should be determined. H 2 O, NaOH, heat. Concept Introduction: Base hydrolysis of an ester produces sodium salt of the carboxylic acid and alcohol. An example is shown below:

Solution Summary: The author explains that the products formed when ethyl benzoate is treated with the following set of reagents should be determined.