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Interpretation:
The ratio of tritium in water in the area to the tritium in a bottle of wine which is 25 years old should be estimated.
Concept introduction:
Activity is defined as the product of rate constant and number of atoms. It is also defined as the rate of decay or expresses number of atoms decays in unit time.
The mathematical expression is given by:
Where, A = activity, k = first order rate constant and N = number of radioactive nuclei.
Activity can be expressed in following units:
1 Bq = 1 atom/s
1 Ci = 3.700 × 1010 atoms/s
The relation between half-life and first order rate constant is given by:
Where, k = first order rate constant and
The activity of sample is directly proportional to the amount of C-14. The mathematical expression is given by:
Where,
t= age of the sample
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Chapter 18 Solutions
Chemistry: Principles and Reactions
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- The isotope S3890r one of the extremely hazardous species in the residues from nuclear power generation. The strontium in a 0.500-g sample diminishes to 0.393 g in 10.0 y. Calculate the half-life.arrow_forwardRecently, the skeleton of King Richard III was found under a parking lot in England. If tissue samples from the skeleton) contain about 93.79% of the carbon-14 expected in living tissue, what year did King Richard III die? The half-life fur carbon-14 is 5730 years.arrow_forwardThe half-life of tritium, 3H, is 12.26 years. Tritium is the radioactive isotope of hydrogen. (a) What is the rate constant for the radioactive decay of tritium, in y1 and s1? (b) What percentage of the original tritium is left after 61.3 years?arrow_forward
- The rate constant for the radioactive decay of 14C is 1.21104 year-1. The products of the decay are nitrogen atoms and electrons (beta particles): C614N714+e rate =k[C614] What is the instantaneous rate of production of N atoms in a sample with a carbon-14 content of 6.5109M?arrow_forward11.17 Ammonia can react with oxygen to produce nitric oxide and water: 4NH3(g)+5O2(g)4NO(g)+6H2O(g) If the rate at which ammonia is consumed in a laboratory experiment is 4.23 ×10-4 mol L_1s_l, at what rate is oxygen consumed? At what rate is NO produced? At what rate is water vapor produced?arrow_forwardConsider this scenario and answer the following questions: Chlorine atoms resulting from decomposition of chloro?uoromethanes, such as CCI2F2, catalyze the decomposition of ozone in the atmosphere. One simplified mechanism for the decomposition is: O3sunlightO2+O O3+CIO2+CIO CIO+OCI+O2 (a) Explain why chlorine atoms are catalysts in the gas-phase transformation: 2O33O2 (b) Nitric oxide is also involved in the decomposition of ozone by the mechanism: O3sunlightO2+O O3+NONO2+O2 NO2+ONO+O2 Is NO a catalyst for the decomposition? Explain your answer.arrow_forward
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