Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 18, Problem 77QAP
Interpretation Introduction

(a)

Interpretation:

The amount of Pu-239 decomposed in 45 minutes in the following decay reaction needs to be calculated.

P94239uU92235 + H24e

Concept introduction:

Radioactive decay follows first order kinetics as per the following relation:

lnXX0 = kt ----(1)where, X0= amount of radioactive substance at t = 0X = amount of substance present at time tk = decay constant

Interpretation Introduction

(b)

Interpretation:

The amount of energy released when 2.475×109g of Pu-239 decomposed in 45 min needs to be calculated

Concept introduction:

The energy change associated with a nuclear reaction is expressed as:

ΔE = Δmc2 ----(2)where, Δm = change in mass = mass of prooducts - mass of reactantsc = speed of light 

Interpretation Introduction

(c)

Interpretation:

The radiation dose in rem received by a man weighing 75 kg and exposed to 1 g of Pu-239 for 45 min needs to be calculated.

Concept introduction:

The biological effect of radiation on tissues is expressed in terms of ‘rems’ i.e. radiation equivalent for man

1 rem = n (no. of rads)where n = factor that reflects the potential for damage by a particular radiationn = 1 for beta and gamma emission

n = 20 for alpha1 rad = 102 J/kg

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Chapter 18 Solutions

Chemistry: Principles and Reactions

Ch. 18 - Prob. 11QAPCh. 18 - Prob. 12QAPCh. 18 - Prob. 13QAPCh. 18 - Prob. 14QAPCh. 18 - Prob. 15QAPCh. 18 - Prob. 16QAPCh. 18 - Prob. 17QAPCh. 18 - Prob. 18QAPCh. 18 - Balance the following equations by filling in the...Ch. 18 - Prob. 20QAPCh. 18 - Prob. 21QAPCh. 18 - Prob. 22QAPCh. 18 - Prob. 23QAPCh. 18 - Prob. 24QAPCh. 18 - Prob. 25QAPCh. 18 - Prob. 26QAPCh. 18 - Prob. 27QAPCh. 18 - Prob. 28QAPCh. 18 - Prob. 29QAPCh. 18 - Prob. 30QAPCh. 18 - Prob. 31QAPCh. 18 - Prob. 32QAPCh. 18 - Prob. 33QAPCh. 18 - Prob. 34QAPCh. 18 - Prob. 35QAPCh. 18 - Prob. 36QAPCh. 18 - Prob. 37QAPCh. 18 - Prob. 38QAPCh. 18 - Prob. 39QAPCh. 18 - Prob. 40QAPCh. 18 - Prob. 41QAPCh. 18 - Prob. 42QAPCh. 18 - Prob. 43QAPCh. 18 - Prob. 44QAPCh. 18 - Prob. 45QAPCh. 18 - Prob. 46QAPCh. 18 - Prob. 47QAPCh. 18 - Prob. 48QAPCh. 18 - Prob. 49QAPCh. 18 - Prob. 50QAPCh. 18 - Prob. 51QAPCh. 18 - Prob. 52QAPCh. 18 - Prob. 53QAPCh. 18 - Prob. 54QAPCh. 18 - Prob. 55QAPCh. 18 - Prob. 56QAPCh. 18 - Prob. 57QAPCh. 18 - Prob. 58QAPCh. 18 - Prob. 59QAPCh. 18 - Prob. 60QAPCh. 18 - Prob. 61QAPCh. 18 - Prob. 62QAPCh. 18 - Prob. 63QAPCh. 18 - Prob. 64QAPCh. 18 - Prob. 65QAPCh. 18 - Prob. 66QAPCh. 18 - Prob. 67QAPCh. 18 - Prob. 68QAPCh. 18 - Prob. 69QAPCh. 18 - Prob. 70QAPCh. 18 - Prob. 71QAPCh. 18 - Prob. 72QAPCh. 18 - Fill in the following table:Ch. 18 - Prob. 74QAPCh. 18 - Prob. 75QAPCh. 18 - Prob. 76QAPCh. 18 - Prob. 77QAPCh. 18 - Prob. 78QAPCh. 18 - Prob. 79QAPCh. 18 - Carbon-14 (C-14) with a half-life of 5730 years...Ch. 18 - Prob. 81QAPCh. 18 - Prob. 82QAP
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