CAREY: ORGANIC CHEMISTRY
CAREY: ORGANIC CHEMISTRY
10th Edition
ISBN: 9781260364002
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 18, Problem 30P
Interpretation Introduction

Interpretation:

Among the given pair, the compound that reacts faster or has the more favorable equilibrium constant for reaction with the indicated reagent is to be identified.

Concept Introduction:

Aldehydes and ketones are reduced most readily by hydride reagents such as LiAlH4 or NaBH4 to form primary and secondary alcohols.

The steric effect results from the larger size of atoms or groups. This effect has occurs from the fact that atoms that made molecules occupy some space and when these atoms come too close together then the energy of the molecule increases due to the atoms that are forced to occupy same space.

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Give the major product of the following reaction. excess 1. OH, H₂O 1.OH H CH3CH2CH21 H 2. A.-H₂O Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.
2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJ
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Chapter 18 Solutions

CAREY: ORGANIC CHEMISTRY

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