EBK CHEMISTRY: AN ATOMS FIRST APPROACH
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 8220100552236
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 18, Problem 21E
Interpretation Introduction

Interpretation: Mode of decay for iron- 53 and iron- 59 , two radioactive isotopes of iron, is to be stated.

Concept introduction: Iron has many radioactive isotopes among which four are stable having mass numbers 54,56,57 and 58 . Two radioactive isotopes of iron are iron- 53 and iron- 59 . Nuclei of radioactive element decompose in various ways. Types of radioactive processes include α particle production, β particle production, γ ray production, electron capture and many others. Beta particle production decay involves the production of beta particle (10e) that is assigned mass number zero.

A helium nucleus 24He is produced in the alpha decay process.

Positron 10e is a particle with mass same as the electron, but its charge is opposite to that of electron.

To determine: The mode of decay for the isotope 53Fe .

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³
fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Chapter 18 Solutions

EBK CHEMISTRY: AN ATOMS FIRST APPROACH

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