(a) Interpretation: The products formed by the Friedel-Craft alkylation of given compound with CH 3 Cl and AlCl 3 are to be drawn. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Question

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Answer 1

Question

Chapter 18, Problem 18.21P

Interpretation Introduction

(a)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−SO3H$ group. This group is strong electron withdrawing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 1

Figure 1

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(b)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−Cl$ group. This group is a strong deactivating group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 2

Figure 2

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(c)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−N(CH3)2$ group. This group is a strong electron releasing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 3

Figure 3

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(d)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are drawn below.

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−NHCOCH3$ group. This group is moderately electron releasing group. Hence, the given compound undergoes Friedel-craft alkylation reaction with $CH3Cl$ and $AlCl3$ as shown in Figure 4.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 4

Figure 4

Conclusion

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are shown in Figure 4.

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Answer 2

Question

Chapter 18, Problem 18.21P

Interpretation Introduction

(a)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−SO3H$ group. This group is strong electron withdrawing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 1

Figure 1

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(b)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−Cl$ group. This group is a strong deactivating group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 2

Figure 2

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(c)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−N(CH3)2$ group. This group is a strong electron releasing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 3

Figure 3

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(d)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are drawn below.

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−NHCOCH3$ group. This group is moderately electron releasing group. Hence, the given compound undergoes Friedel-craft alkylation reaction with $CH3Cl$ and $AlCl3$ as shown in Figure 4.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 4

Figure 4

Conclusion

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are shown in Figure 4.

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Answer 3

Question

Chapter 18, Problem 18.21P

Interpretation Introduction

(a)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−SO3H$ group. This group is strong electron withdrawing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 1

Figure 1

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(b)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−Cl$ group. This group is a strong deactivating group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 2

Figure 2

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(c)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−N(CH3)2$ group. This group is a strong electron releasing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 3

Figure 3

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(d)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are drawn below.

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−NHCOCH3$ group. This group is moderately electron releasing group. Hence, the given compound undergoes Friedel-craft alkylation reaction with $CH3Cl$ and $AlCl3$ as shown in Figure 4.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 4

Figure 4

Conclusion

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are shown in Figure 4.

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Answer 4

Question

Chapter 18, Problem 18.21P

Interpretation Introduction

(a)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−SO3H$ group. This group is strong electron withdrawing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 1

Figure 1

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(b)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−Cl$ group. This group is a strong deactivating group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 2

Figure 2

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(c)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−N(CH3)2$ group. This group is a strong electron releasing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 3

Figure 3

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(d)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are drawn below.

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−NHCOCH3$ group. This group is moderately electron releasing group. Hence, the given compound undergoes Friedel-craft alkylation reaction with $CH3Cl$ and $AlCl3$ as shown in Figure 4.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 4

Figure 4

Conclusion

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are shown in Figure 4.

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Answer 5

Chapter 18, Problem 18.21P

Interpretation Introduction

(a)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−SO3H$ group. This group is strong electron withdrawing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 1

Figure 1

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(b)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−Cl$ group. This group is a strong deactivating group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 2

Figure 2

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(c)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−N(CH3)2$ group. This group is a strong electron releasing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 3

Figure 3

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Interpretation Introduction

(d)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are drawn below.

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−NHCOCH3$ group. This group is moderately electron releasing group. Hence, the given compound undergoes Friedel-craft alkylation reaction with $CH3Cl$ and $AlCl3$ as shown in Figure 4.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 4

Figure 4

Conclusion

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are shown in Figure 4.

Answer 6

Chapter 18, Problem 18.21P

Interpretation Introduction

(a)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−SO3H$ group. This group is strong electron withdrawing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 1

Figure 1

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 7

Chapter 18, Problem 18.21P

Interpretation Introduction

(a)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 8

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−SO3H$ group. This group is strong electron withdrawing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 1

Figure 1

Answer 13

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 14

Interpretation Introduction

(b)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−Cl$ group. This group is a strong deactivating group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 2

Figure 2

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 15

Interpretation Introduction

(b)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 16

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−Cl$ group. This group is a strong deactivating group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 2

Figure 2

Answer 21

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 22

Interpretation Introduction

(c)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−N(CH3)2$ group. This group is a strong electron releasing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 3

Figure 3

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 23

Interpretation Introduction

(c)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 24

Expert Solution

Answer to Problem 18.21P

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−N(CH3)2$ group. This group is a strong electron releasing group. Hence, the Friedel-craft alkylation reaction will not take place on reaction of given compound with $CH3Cl$ and $AlCl3$ .

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 3

Figure 3

Answer 29

Conclusion

The given compound does not undergo Friedel-craft alkylation reaction on reaction with $CH3Cl$ and $AlCl3$ .

Answer 30

Interpretation Introduction

(d)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Expert Solution

Answer to Problem 18.21P

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are drawn below.

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−NHCOCH3$ group. This group is moderately electron releasing group. Hence, the given compound undergoes Friedel-craft alkylation reaction with $CH3Cl$ and $AlCl3$ as shown in Figure 4.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 18, Problem 18.21P , additional homework tip 4

Figure 4

Conclusion

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are shown in Figure 4.

Answer 31

Interpretation Introduction

(d)

Interpretation: The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 32

Expert Solution

Answer to Problem 18.21P

The products formed by the Friedel-Craft alkylation of given compound with $CH3Cl$ and $AlCl3$ are drawn below.

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The Friedel-craft alkylation of aromatic compound with $CH3Cl$ in presence of $AlCl3$ involves substitution of $CH3$ group. Friedel-craft alkylation reaction does not take place when an aromatic ring is substituted by a strong electron releasing or strong electron withdrawing group.

The structure of given compound shows that benzene ring is substituted by $−NHCOCH3$ group. This group is moderately electron releasing group. Hence, the given compound undergoes Friedel-craft alkylation reaction with $CH3Cl$ and $AlCl3$ as shown in Figure 4.