Concept explainers
(a)
Interpretation:
Change in equilibrium position of the given reaction in lungs has to be interpreted.
Concept Introduction:
Le Chatelier principle states that, whenever a system at equilibrium is disturbed, the system will undergo reactions and try to cancel that effect and retain equilibrium. Here the disturbance means change in concentration of any of the component, change in temperature, pressure or volume.
(b)
Interpretation:
Change in equilibrium position of the given reaction in oxygen deficient cells has to be interpreted.
Concept Introduction:
Le Chatelier principle states that, whenever a system at equilibrium is disturbed, the system will undergo reactions and try to cancel that effect and reattain equilibrium. Here the disturbance means change in concentration of any of the component, change in temperature, pressure or volume.
(c)
Interpretation:
The effect of decrease in concentration of
Concept Introduction:
Le Chatelier principle states that, whenever a system at equilibrium is disturbed, the system will undergo reactions and try to cancel that effect and reattain equilibrium. Here the disturbance means change in concentration of any of the component, change in temperature, pressure or volume.
(d)
Interpretation:
The effect of increase in concentration of
Concept Introduction:
Le Chatelier principle states that, whenever a system at equilibrium is disturbed, the system will undergo reactions and try to cancel that effect and reattain equilibrium. Here the disturbance means change in concentration of any of the component, change in temperature, pressure or volume.

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Chapter 18 Solutions
CHEMISTRY:MOLECULAR...(LL) W/ALEKS
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- Draw the mechanism for the following Friedel-Craft reaction. AlBr3 Brarrow_forward(a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Consider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Given the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardk₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forward
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