Chemistry: The Molecular Nature of Matter and Change
Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 18, Problem 18.117P
Interpretation Introduction

Interpretation:

The reason has to be explained for aqueous NaF is basic but aqueous NaCl is neutral.

Concept introduction:

The aqueous of acidic, basic or neutral is identified by using following method.

The depending on an ion’s ability to react with water,

If the solution is neutral, then the anion is from strong acid and the cation from strong base.

If the solution is acidic, then the anion is from strong acid (or highly charged metal cation) and the cation from weak base.

If the solution is basic, then the anion is from weak acid and the cation from strong base.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.
е. Д CH3 D*, D20
C. NaOMe, Br Br

Chapter 18 Solutions

Chemistry: The Molecular Nature of Matter and Change

Ch. 18.2 - Prob. 18.1AFPCh. 18.2 - Prob. 18.1BFPCh. 18.2 - Prob. 18.2AFPCh. 18.2 - Prob. 18.2BFPCh. 18.2 - Prob. 18.3AFPCh. 18.2 - Prob. 18.3BFPCh. 18.3 - Prob. 18.4AFPCh. 18.3 - Prob. 18.4BFPCh. 18.4 - Prob. 18.5AFPCh. 18.4 - Prob. 18.5BFP
Ch. 18.5 - Prob. 18.6AFPCh. 18.5 - Prob. 18.6BFPCh. 18.5 - Prob. 18.7AFPCh. 18.5 - Prob. 18.7BFPCh. 18.5 - Prob. 18.8AFPCh. 18.5 - Prob. 18.8BFPCh. 18.5 - Prob. 18.9AFPCh. 18.5 - Prob. 18.9BFPCh. 18.7 - Prob. 18.10AFPCh. 18.7 - Prob. 18.10BFPCh. 18.7 - Prob. 18.11AFPCh. 18.7 - Prob. 18.11BFPCh. 18.8 - Prob. 18.12AFPCh. 18.8 - Prob. 18.12BFPCh. 18.8 - Prob. 18.13AFPCh. 18.8 - Prob. 18.13BFPCh. 18.10 - Prob. 18.14AFPCh. 18.10 - Prob. 18.14BFPCh. 18 - Prob. 18.1PCh. 18 - Prob. 18.2PCh. 18 - Prob. 18.3PCh. 18 - Prob. 18.4PCh. 18 - Prob. 18.5PCh. 18 - Prob. 18.6PCh. 18 - Which of the following are Arrhenius...Ch. 18 - Prob. 18.8PCh. 18 - Prob. 18.9PCh. 18 - A Brønstcd-Lowry acid-base reaction proceeds in...Ch. 18 - Prob. 18.11PCh. 18 - Give the formula of the conjugate...Ch. 18 - Give the formula of the conjugate base: Ch. 18 - Give the formula of the conjugate...Ch. 18 - Prob. 18.15PCh. 18 - Prob. 18.16PCh. 18 - In each equation, label the acids, bases, and...Ch. 18 - Prob. 18.18PCh. 18 - Prob. 18.19PCh. 18 - Prob. 18.20PCh. 18 - Prob. 18.21PCh. 18 - Prob. 18.22PCh. 18 - The following aqueous species constitute two...Ch. 18 - Prob. 18.24PCh. 18 - Use Figure 18.8 to determine whether Kc > 1...Ch. 18 - Prob. 18.26PCh. 18 - Prob. 18.27PCh. 18 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Prob. 18.30PCh. 18 - Which solution has the higher pH? Explain. A 0.1 M...Ch. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - Prob. 18.34PCh. 18 - Prob. 18.35PCh. 18 - Prob. 18.36PCh. 18 - Prob. 18.37PCh. 18 - Prob. 18.38PCh. 18 - Prob. 18.39PCh. 18 - The two molecular scenes shown depict the relative...Ch. 18 - Prob. 18.41PCh. 18 - Prob. 18.42PCh. 18 - Prob. 18.43PCh. 18 - Prob. 18.44PCh. 18 - Prob. 18.45PCh. 18 - (a) What is the pH of 0.0111 M NaOH? Is the...Ch. 18 - (a) What is the pH of 0.0333 M HNO3? Is the...Ch. 18 - Prob. 18.48PCh. 18 - (a) What is the pH of 7.52×10−4 M CsOH? Is the...Ch. 18 - Prob. 18.50PCh. 18 - Prob. 18.51PCh. 18 - Prob. 18.52PCh. 18 - Prob. 18.53PCh. 18 - Prob. 18.54PCh. 18 - Prob. 18.55PCh. 18 - Prob. 18.56PCh. 18 - Prob. 18.57PCh. 18 - Prob. 18.58PCh. 18 - Prob. 18.59PCh. 18 - Prob. 18.60PCh. 18 - Prob. 18.61PCh. 18 - Prob. 18.62PCh. 18 - Prob. 18.63PCh. 18 - Prob. 18.64PCh. 18 - Prob. 18.65PCh. 18 - Prob. 18.66PCh. 18 - Prob. 18.67PCh. 18 - Hypochlorous acid, HClO, has a pKa of 7.54. What...Ch. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - Prob. 18.71PCh. 18 - Prob. 18.72PCh. 18 - Prob. 18.73PCh. 18 - Prob. 18.74PCh. 18 - Prob. 18.75PCh. 18 - Prob. 18.76PCh. 18 - Prob. 18.77PCh. 18 - Prob. 18.78PCh. 18 - Prob. 18.79PCh. 18 - Prob. 18.80PCh. 18 - Prob. 18.81PCh. 18 - Formic acid, HCOOH, the simplest carboxylic acid,...Ch. 18 - Across a period, how does the electronegativity of...Ch. 18 - How does the atomic size of a nonmetal affect the...Ch. 18 - Prob. 18.85PCh. 18 - Prob. 18.86PCh. 18 - Prob. 18.87PCh. 18 - Prob. 18.88PCh. 18 - Choose the stronger acid in each of the following...Ch. 18 - Prob. 18.90PCh. 18 - Prob. 18.91PCh. 18 - Prob. 18.92PCh. 18 - Use Appendix C to choose the solution with the...Ch. 18 - Prob. 18.94PCh. 18 - Prob. 18.95PCh. 18 - Prob. 18.96PCh. 18 - Prob. 18.97PCh. 18 - Prob. 18.98PCh. 18 - Prob. 18.99PCh. 18 - Prob. 18.100PCh. 18 - Prob. 18.101PCh. 18 - Prob. 18.102PCh. 18 - Prob. 18.103PCh. 18 - Prob. 18.104PCh. 18 - Prob. 18.105PCh. 18 - Prob. 18.106PCh. 18 - Prob. 18.107PCh. 18 - What is the pKb of ? What is the pKa of the...Ch. 18 - Prob. 18.109PCh. 18 - Prob. 18.110PCh. 18 - Prob. 18.111PCh. 18 - Prob. 18.112PCh. 18 - Prob. 18.113PCh. 18 - Prob. 18.114PCh. 18 - Prob. 18.115PCh. 18 - Prob. 18.116PCh. 18 - Prob. 18.117PCh. 18 - Prob. 18.118PCh. 18 - Prob. 18.119PCh. 18 - Prob. 18.120PCh. 18 - Prob. 18.121PCh. 18 - Prob. 18.122PCh. 18 - Prob. 18.123PCh. 18 - Explain with equations and calculations, when...Ch. 18 - Prob. 18.125PCh. 18 - Prob. 18.126PCh. 18 - Rank the following salts in order of increasing pH...Ch. 18 - Rank the following salts in order of decreasing pH...Ch. 18 - Prob. 18.129PCh. 18 - Prob. 18.130PCh. 18 - Prob. 18.131PCh. 18 - Prob. 18.132PCh. 18 - Prob. 18.133PCh. 18 - Prob. 18.134PCh. 18 - Prob. 18.135PCh. 18 - Prob. 18.136PCh. 18 - Prob. 18.137PCh. 18 - Prob. 18.138PCh. 18 - Which are Lewis acids and which are Lewis...Ch. 18 - Prob. 18.140PCh. 18 - Prob. 18.141PCh. 18 - Prob. 18.142PCh. 18 - Prob. 18.143PCh. 18 - Classify the following as Arrhenius,...Ch. 18 - Chloral (Cl3C—CH=O) forms a monohydrate, chloral...Ch. 18 - Prob. 18.146PCh. 18 - Prob. 18.147PCh. 18 - Prob. 18.148PCh. 18 - Prob. 18.149PCh. 18 - Prob. 18.150PCh. 18 - Prob. 18.151PCh. 18 - Prob. 18.152PCh. 18 - Prob. 18.153PCh. 18 - The strength of an acid or base is related to its...Ch. 18 - Prob. 18.155PCh. 18 - Three beakers contain 100. mL of 0.10 M HCl,...Ch. 18 - Prob. 18.157PCh. 18 - Prob. 18.158PCh. 18 - Prob. 18.159PCh. 18 - Prob. 18.160PCh. 18 - Prob. 18.161PCh. 18 - What is the pH of a vinegar with 5.0% (w/v) acetic...Ch. 18 - Prob. 18.163PCh. 18 - Prob. 18.164PCh. 18 - Prob. 18.165PCh. 18 - Prob. 18.166PCh. 18 - Prob. 18.167PCh. 18 - Prob. 18.168PCh. 18 - Prob. 18.169PCh. 18 - Prob. 18.170PCh. 18 - Prob. 18.171PCh. 18 - Prob. 18.172PCh. 18 - Prob. 18.173PCh. 18 - Prob. 18.174PCh. 18 - Prob. 18.175PCh. 18 - Prob. 18.176PCh. 18 - Prob. 18.177PCh. 18 - Prob. 18.178PCh. 18 - Prob. 18.179PCh. 18 - Prob. 18.180PCh. 18 - Prob. 18.181PCh. 18 - Prob. 18.182PCh. 18 - Prob. 18.183PCh. 18 - Drinking water is often disinfected with Cl2,...Ch. 18 - Prob. 18.185P
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