A metal salt with the formula MCl 2 crystallizes from water to form a solid with the composition MCl 2 ⋅ 6 H 2 O . The equilibrium vapor pressure of water above this solid at 298 K is 18.3 mmHg. What is the value of Δ G for the reaction MCl 2 ⋅ 6 H 2 O( s ) ⇌ MCl 2 ( s ) + 6 H 2 O ( g ) when the pressure of water vapor is 18.3 mmHg? When the pressure of water vapor is 760.0 mmHg?
A metal salt with the formula MCl 2 crystallizes from water to form a solid with the composition MCl 2 ⋅ 6 H 2 O . The equilibrium vapor pressure of water above this solid at 298 K is 18.3 mmHg. What is the value of Δ G for the reaction MCl 2 ⋅ 6 H 2 O( s ) ⇌ MCl 2 ( s ) + 6 H 2 O ( g ) when the pressure of water vapor is 18.3 mmHg? When the pressure of water vapor is 760.0 mmHg?
Solution Summary: The author explains how to determine the value of G r x n at various pressures.
A metal salt with the formula MCl2 crystallizes from water to form a solid with the composition
MCl
2
⋅
6
H
2
O
. The equilibrium vapor pressure of water above this solid at 298 K is 18.3 mmHg. What is the value of
Δ
G
for the reaction
MCl
2
⋅
6
H
2
O(
s
)
⇌
MCl
2
(
s
)
+
6
H
2
O
(
g
)
when the pressure of water vapor is 18.3 mmHg? When the pressure of water vapor is 760.0 mmHg?
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The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3
best described as a hybrid of several contributing resonance forms, two of which
are shown here.
HO
:0:
:Ö:
HO
+
Bicarbonate is crucial for the control of body pH (for example, blood pH:
7.4). A more self-indulgent use is in baking soda, where it serves as a
source of CO2 CO₂ 2 gas, which gives bread and pastry their fluffy
constituency.
(i) Draw at least one additional resonance form.
=
(ii) Using curved "electron-pushing" arrows, show how these Lewis structures may
be interconverted by movement of electron pairs. (iii) Determine which form or
forms will be the major contributor(s) to the real structure of bicarbonate,
explaining your answer on the basis of the criteria in Section 1-5.
Which of these is the best use of a volumetric flask?
measuring how much liquid it contains
delivering a precise amount of liquid to another container
holding solutions
making solutions of precise concentration
Chapter 18 Solutions
Solutions Manual For Chemistry: Structure And Properties
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