Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
8th Edition
ISBN: 9780134581064
Author: Bruice, Paula Yurkanis
Publisher: Prentice Hall
expand_more
expand_more
format_list_bulleted
Question
Chapter 17.1, Problem 3P
Interpretation Introduction
Interpretation: Remove a proton from the alpha carbon of
Concept introduction: The electrons left behind when a proton is removed from the alpha carbon of an amide are not readily delocalized. This is because the nitrogen of the
Thus the lone pair on the alpha carbon and the lone pair on the nitrogen compete for the delocalization onto the same oxygen.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Experiment 1
Data Table 1: Conservation of Mass - Initial Mass
Data Table 1
Data Table 2
Data Table 3
Data Table 4
Panel 1
Photo 1
Data Table 5
Reaction Mass of test tube and 5.0% HC₂H₂O2 (g)
#
(A)
(B)
Mass of NaHCO, (g) Mass of balloon and NaHCO, (g)
(C)
0.10
1
0829
14.38g
0.20
2
0.929
14.29g
0.35
1.00g
3
14.25g
0.50
1.14g
14.29
Experiment 1
Data Table 2: Moles of HC2H3O2
Reaction Volume of Mass of
Moles of HC₂H₂O₂
5.0%
Vinegar
(g)
(ML)
5.0
0.25
0042 mol
2
5.0
0.25
0042 mol
3
5.0
0.25
0042 mol
5.0
0.25
0042 mol
Experiment 1
Data Table 3: Moles of NaHCO3
Reaction Mass of NaHCO (g)
10g
20g
35g
50g
Experiment 1
Data Table 4: Theoretical Yield of CO₂
Reaction #
1
2
3
Experiment 1
Total mass before reaction (g)
(D=A+C)
15.29
15.21g
15.25g
15.349
Exercise 1
Data Table 1
Data Table 2
Data Table 3
Data Table 4
Panel 1
Photo 1
Data Table 5
Exercise 1-
Data Table 1
Data Table 2
DataTable 3
Data Table 4
Panel 1
Photo 1
Data Table 5
Exercise 1-
Moles of NaHCO
0012 mol
0025 mol
0044 mol
0062 mol…
The chemical reaction you investigated is a two-step reaction. What type of reaction occurs in each step? How did you determine your answer?
What is the relationship between the limiting reactant and theoretical yield of CO2?
Chapter 17 Solutions
Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
Ch. 17.1 - Prob. 1PCh. 17.1 - Prob. 2PCh. 17.1 - Prob. 3PCh. 17.1 - Prob. 4PCh. 17.1 - Rank the compounds in each of the following groups...Ch. 17.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 17.3 - Draw the enol tautomers for each of the following...Ch. 17.3 - Prob. 8PCh. 17.4 - Prob. 9PCh. 17.4 - Prob. 10P
Ch. 17.5 - Show how the following compounds can be prepared...Ch. 17.6 - What compound is formed when a dilute solution of...Ch. 17.7 - Prob. 13PCh. 17.7 - Prob. 14PCh. 17.7 - How many stereoisomers are obtained from each of...Ch. 17.7 - Prob. 16PCh. 17.8 - Prob. 17PCh. 17.9 - Prob. 18PCh. 17.9 - What reagents should be used to prepare the...Ch. 17.10 - Prob. 20PCh. 17.10 - What aldehyde or ketone would be obtained when...Ch. 17.11 - Prob. 22PCh. 17.11 - How could you prepare the following compound using...Ch. 17.12 - Prob. 25PCh. 17.12 - What two carbonyl compound are required for the...Ch. 17.12 - Propose a mechanism for the following reaction:Ch. 17.13 - Draw the products of the following reactions:Ch. 17.13 - Prob. 29PCh. 17.13 - Prob. 30PCh. 17.14 - Prob. 31PCh. 17.15 - Write the mechanism for the reaction of a...Ch. 17.15 - Prob. 33PCh. 17.15 - Prob. 34PCh. 17.15 - Draw the product of the reaction of each of the...Ch. 17.16 - Draw the product obtained by heating each pair of...Ch. 17.16 - What two carbonyl compounds are needed to...Ch. 17.17 - Prob. 38PCh. 17.18 - Prob. 39PCh. 17.18 - Prob. 40PCh. 17.19 - Prob. 41PCh. 17.20 - Prob. 43PCh. 17.21 - Propose a mechanism for the formation of...Ch. 17.21 - Prob. 45PCh. 17.21 - a. If the biosynthesis of palmitic acid were...Ch. 17.21 - Prob. 47PCh. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Number the following compounds in order of...Ch. 17 - The 1H NMR chemical shifts of nitromethane,...Ch. 17 - Prob. 52PCh. 17 - Draw the products of the following reactions: a....Ch. 17 - A racemic mixture of 2-methyl-1-phenyl-1-butanone...Ch. 17 - Draw the products of the following reaction:Ch. 17 - Prob. 56PCh. 17 - Prob. 57PCh. 17 - In the presence of excess base and excess halogen,...Ch. 17 - Identify A-L. (Hint: A shows three singles in its...Ch. 17 - Using cyclopentanone as the reactant, show the...Ch. 17 - Show how 4-methyl-3-hexanol can be synthesized...Ch. 17 - Show how the following compound can be synthesized...Ch. 17 - Show how the following compounds can be prepared...Ch. 17 - Prob. 64PCh. 17 - Prob. 65PCh. 17 - Indicate how each of the following compounds can...Ch. 17 - Prob. 67PCh. 17 - The ketone whose 1H NMR spectrum is shown here was...Ch. 17 - Indicate how the following compounds can be...Ch. 17 - Compound A with molecular formula C6H10 has two...Ch. 17 - Prob. 71PCh. 17 - Draw the products of the following reactions:Ch. 17 - Prob. 73PCh. 17 - a. Show how the amino acid alanine can be...Ch. 17 - Show how the following compounds can be...Ch. 17 - Prob. 76PCh. 17 - Explain why the following bromoketone forms...Ch. 17 - Prob. 78PCh. 17 - A carboxylic arid is formed when an -haloketone...Ch. 17 - An , -unsaturated carbonyl compound can be...Ch. 17 - What carbonyl compounds are required to prepare a...Ch. 17 - Prob. 82PCh. 17 - A Cannizzaro reaction is the reaction of an...Ch. 17 - Propose a mechanism for each of the following...Ch. 17 - The following reaction is known as the benzoni...Ch. 17 - Prob. 86PCh. 17 - Prob. 87PCh. 17 - Prob. 88PCh. 17 - Prob. 89PCh. 17 - Prob. 90PCh. 17 - Propose a mechanism for the following reaction:Ch. 17 - What reagents are required to convert the reactant...Ch. 17 - Starting with bromocyclohexane, how can each of...Ch. 17 - Describe how the following compounds can be...Ch. 17 - Prob. 4PCh. 17 - Describe three ways to synthesize the following...Ch. 17 - Explain why 92% of 2.4-pentanedione exists as the...Ch. 17 - Describe how the following compound can be...Ch. 17 - Prob. 8PCh. 17 - Prob. 9PCh. 17 - Prob. 10PCh. 17 - Show how the following compounds can be...
Knowledge Booster
Similar questions
- From your calculations, which reaction experiment had closest to stoichiometric quantities? How many moles of NaHCO3 and HC2H3O2 were present in this reaction?arrow_forward18. Arrange the following carbocations in order of decreasing stability. 1 2 A 3124 B 4213 C 2431 D 1234 E 2134 SPL 3 4arrow_forwardAcetic acid is added to DI water at an initial concentration of 10 -6 M (Ka=1.8x10-5) A. Using the "ICE" Method, what would the pH be at equilibrium? State assumptions and show your work. B. Using the simultaneous equations method, what would the pH be at equilibrium? Show your workarrow_forward
- 1. Show that the change in entropy for a fixed amount of ideal gas held at a constant temperature undergoing a volume change is given by the simple equation AS = NkB In Hint: Start with the equation M dS = du + (Œ) dv - Ž (#) an, dU du+av-dN; j=1 Why doesn't the equation for the entropy of an ideal gas depend on the strength of the intermolecular forces for the gas?arrow_forward2. Make an ice cube at 1 bar pressure by freezing an amount of liquid water that is 2 cm x 2 cm x 2 cm in volume. The density of liquid water at 0 °C is 1.000 g cm³ and the density of ice at 0 °C is 0.915 g cm³. Note that this difference in density is the reason your water pipes burst if they freeze and why you shouldn't forget to take your bottle of pop out of the freezer if you put it in there to try and cool it down faster. A. What is the work of expansion upon freezing? B. Is work done on the system or by the system?arrow_forwardI have a excitation/emission spectra of a quinine standard solution here, and I'm having trouble interpreting it. the red line is emission the blue line is excitation. i'm having trouble interpreting properly. just want to know if there is any evidence of raman or rayleigh peaks in the spectra.arrow_forward
- Give the major product of the following reaction. excess 1. OH, H₂O 1.OH H CH3CH2CH21 H 2. A.-H₂O Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.arrow_forward2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forwardci Draw the major product(s) of the following reactions: (3 pts) CH3 HNO3/H2SO4 HNO3/ H2SO4 OCH3 (1 pts)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning