CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 17, Problem 90AP
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An analytical chemist is titrating 249.7 mL of a 1.000M solution of butanoic acid (HC,H,CO,) with a 0.8200M solution of NaOH. The p K, of butanoic acid is
4.82. Calculate the pH of the acid solution after the chemist has added 117.2 mL of the NaOH solution to it.
Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of NaOH solution added.
Round your answer to 2 decimal places.
pH = ]
?
%3D
An analytical chemist is titrating 249.7 mL of a 1.000M solution of butanoic acid (HC,H,CO,) with a 0.8200M solution of NaOH. The p K, of butanoic acid is
a
4.82. Calculate the pH of the acid solution after the chemist has added 117.2 mL of the NaOH solution to it.
Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of NaOH solution added.
Round your answer to 2 decimal places.
pH = U
An analytical chemist is titrating 56.7 mL of a 0.4900M solution of formic acid (H,CO,) with a 0.7500M solution of KOH.
The p K, of formic acid is 3.74. Calculate the pH of the acid solution after the chemist has added 44.2 mL of the KOH
solution to it.
Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of
KOH solution added.
Round your answer to 2 decimal places.
pH
%3D
Chapter 17 Solutions
CHEMISTRY >CUSTOM<
Ch. 17.1 - Practice ProblemATTEMPT Determine the pH at 25°C...Ch. 17.1 - Practice ProblemBUILD Determine the pH at 25°C of...Ch. 17.1 - Prob. 1PPCCh. 17.1 - Which of the following would cause a decrease in...Ch. 17.1 - What is the pH of a solution prepared by adding 0...Ch. 17.2 - Practice Problem ATTEMPT
Calculate the pH of 1 L...Ch. 17.2 - Practice Problem BUILD
How much must be added to...Ch. 17.2 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 17.2 - 17.2.1 Which of the following combinations can be...Ch. 17.2 - What is the pH of a buffer that is 0.76 M in HF...
Ch. 17.2 - 17.2.3 Consider 1 L of a buffer that is 0.85 M in...Ch. 17.2 - Consider 1 L of a buffer that is 1.5 M in...Ch. 17.2 - The solutions shown contain one or more of the...Ch. 17.2 - Prob. 6CPCh. 17.3 - Practice ProblemATTEMPT Select an appropriate acid...Ch. 17.3 - Prob. 1PPBCh. 17.3 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 17.3 - 17.3.1 For which of the following titrations will...Ch. 17.3 - 17.3.2 Calculate the pH at the equivalence point...Ch. 17.3 - Prob. 3CPCh. 17.3 - Calculate the pH after the addition of 35 mL of...Ch. 17.3 - Prob. 5CPCh. 17.3 - Prob. 6CPCh. 17.3 - Prob. 7CPCh. 17.3 - Prob. 8CPCh. 17.4 - Practice ProblemATTEMPT For the titration of 10.0...Ch. 17.4 - Practice ProblemBUILD For the titration of 25.0 mL...Ch. 17.4 - Prob. 1PPCCh. 17.4 - Prob. 1CPCh. 17.4 - Prob. 2CPCh. 17.4 - Prob. 3CPCh. 17.4 - Prob. 4CPCh. 17.4 - Prob. 5CPCh. 17.5 - Practice Problem ATTEMPT Calculate the pH at the...Ch. 17.5 - Practice Problem BUILD
A 50.0-mL quantity of a...Ch. 17.5 - Prob. 1PPCCh. 17.5 - 17.5.1 Calculate the molar solubility of AgCl in...Ch. 17.5 - Prob. 2CPCh. 17.5 - Prob. 3CPCh. 17.6 - Practice Problem ATTEMPT
Referring to Table 17.3,...Ch. 17.6 - Practice Problem BUILD
For which of the bases in...Ch. 17.6 - Practice Problem CONCEPTUALIZE
The diagram shows...Ch. 17.6 - Prob. 1CPCh. 17.6 - 17.6.2 Barium nitrate is added slowly to a...Ch. 17.7 - Prob. 1PPACh. 17.7 - Prob. 1PPBCh. 17.7 - Prob. 1PPCCh. 17.8 - Prob. 1PPACh. 17.8 - Prob. 1PPBCh. 17.8 - Prob. 1PPCCh. 17.9 - Prob. 1PPACh. 17.9 - Practice Problem BUILD What is the maximum mass...Ch. 17.9 - Prob. 1PPCCh. 17.10 - Practice ProblemATTEMPT Calculate the molar...Ch. 17.10 - Practice ProblemBUILD Arrange the following salts...Ch. 17.10 - Practice Problem CONCEPTUALIZE The diagram on the...Ch. 17.11 - Practice Problem ATTEMPT Determine if the...Ch. 17.11 - Practice Problem BUILD
Other than those in Sample...Ch. 17.11 - Practice Problem CONCEPTUALIZE
If an ionic...Ch. 17.12 - Practice ProblemATTEMPT In the presence of aqueous...Ch. 17.12 - Prob. 1PPBCh. 17.12 - Prob. 1PPCCh. 17.13 - Practice ProblemATTEMPT Lead(II) nitrate is added...Ch. 17.13 - Prob. 1PPBCh. 17.13 - Prob. 1PPCCh. 17 - Which of the acids in Table 16.6 can be used to...Ch. 17 - What molar ratio of sodium cyanide to hydrocyanic...Ch. 17 - How many moles of sodium benzoate must be added to...Ch. 17 - How much sodium fluoride must be dissolved in 250...Ch. 17 - Use Le Châtelier’s principle to explain how the...Ch. 17 - 17.2 Describe the effect on pH (increase,...Ch. 17 - Prob. 3QPCh. 17 - The p K a values of two monoprotic acids HA and HB...Ch. 17 - 17.5 Determine the pH of (a) a solution and (b) a...Ch. 17 - Determine the pH of (a) a 0 .20 M NH 3 solution,...Ch. 17 - Prob. 7QPCh. 17 - Prob. 8QPCh. 17 - Prob. 9QPCh. 17 - Prob. 10QPCh. 17 - Prob. 11QPCh. 17 - 17.12 What is the pH of the buffer
Ch. 17 - The pH of a sodium acetate-acetic acid buffer is...Ch. 17 - The pH of blood plasma is 7.40. Assuming the...Ch. 17 - 17.15 Calculate the pH of the buffer. What is the...Ch. 17 - 17.16 Calculate the of 1.00 L of the buffer ...Ch. 17 - Which of the following solutions can act as a...Ch. 17 - Which of the following solutions can act as a...Ch. 17 - A diprotic acid. H 2 A , has the following...Ch. 17 - Prob. 20QPCh. 17 - 17.21 The following diagrams contain one or more...Ch. 17 - The following diagrams represent solutions...Ch. 17 - Briefly describe what happens in an acid-base...Ch. 17 - Prob. 24QPCh. 17 - Explain how an acid-base indicator works in a...Ch. 17 - Prob. 26QPCh. 17 - A 0.2688-g sample of a monoprotic acid neutralizes...Ch. 17 - Prob. 28QPCh. 17 - 17.29 In a titration experiment, 12.5 mL of ...Ch. 17 - 17.30 In a titration experiment. 20.4 mL of 0.883...Ch. 17 - A 0.1276-g sample of an unknown monoprotic acid...Ch. 17 - Prob. 32QPCh. 17 - Calculate the pH at the equivalence point for the...Ch. 17 - Calculate the pH at the equivalence point for the...Ch. 17 - 17.35 A 25.0-mL solution of 0.100 M is titrated...Ch. 17 - 17.36 A 10.0-ml solution of 0.300 M is titrated...Ch. 17 - Prob. 37QPCh. 17 - Prob. 38QPCh. 17 - 17.39 The ionization constant of an indicator is...Ch. 17 - The K a of a certain indicator is 2.0 × 10 − 6 ....Ch. 17 - 17.41 The following diagrams represent solutions...Ch. 17 - The following diagrams represent solutions at...Ch. 17 - Use BaS O 4 to distinguish between the terms...Ch. 17 - 17.44 Why do we usually not quote the values for...Ch. 17 - 17.45 Write balanced equations and solubility...Ch. 17 - 17.46 Write the solubility product expression for...Ch. 17 - How can we predict whether a precipitate will form...Ch. 17 - 17.48 Silver chloride has a larger than silver...Ch. 17 - 17.49 Calculate the concentration of ions in the...Ch. 17 - From the solubility data given, calculate the...Ch. 17 - The molar solubility of MnCO 3 is 4 .2 × 10 -6 M ....Ch. 17 - The solubility of an ionic compound MX ( molar...Ch. 17 - The solubility of an ionic compound M 2 X 3 (...Ch. 17 - Using data from Table 17.4, calculate the molar...Ch. 17 - What is the pH of a saturated zinc hydroxide...Ch. 17 - The pH of a saturated solution of a metal...Ch. 17 - If 20.0 mL of 0.10 M Ba ( NO 3 ) 2 is added to...Ch. 17 - 17.58 A volume of 75 mL of 0.060 M NaF is mixed...Ch. 17 - 17.59 How does the common ion effect influence...Ch. 17 - The molar solubility of AgCl in 6.5 × 10 − 3 M...Ch. 17 - 17.61 Give an example to illustrate the general...Ch. 17 - How many grams of CaCO 3 will dissolve in 3 .0 ×...Ch. 17 - The solubility product of PbBr 2 is 8 .9 × 10 -6 ....Ch. 17 - Calculate the molar solubility of AgCl in a 1.00-L...Ch. 17 - 17.65 Calculate the molar solubility of in (a)...Ch. 17 - Which of the following ionic compounds will be...Ch. 17 - Which of the following will be more soluble in...Ch. 17 - Compare the molar solubility of Mg ( OH ) 2 in...Ch. 17 - Calculate the molar solubility of Fe ( OH ) 2 in a...Ch. 17 - 17.70 The solubility product of . What minimum ...Ch. 17 - Calculate whether or not a precipitate will form...Ch. 17 - 17.72 If 2.50 g of is dissolved in what are the...Ch. 17 - Calculate the concentrations of Cd 2+ , Cd ( CN )...Ch. 17 - If NaOH is added to 0 .010 M Al 3+ . which will be...Ch. 17 - Calculate the molar solubility of AgI in a 1 .0 M...Ch. 17 - Both Ag - and Zn 2- form complex ions with NH 3 ....Ch. 17 - 17.77 Explain, with balanced ionic equations, why...Ch. 17 - Outline the general procedure of qualitative...Ch. 17 - Give two examples of metal ions m each group (1...Ch. 17 - Solid NaI is slowly added to a solution that is 0...Ch. 17 - Find the approximate pH range suitable for the...Ch. 17 - 17.82 In a group 1 analysis, a student obtained a...Ch. 17 - 17.83 In a group 1 analysis, a student adds acid...Ch. 17 - Both KCl and XH 4 Cl are white solids. Suggest one...Ch. 17 - Describe a simple test that would allow you to...Ch. 17 - 17.86 The buffer range is defined by the equation...Ch. 17 - The p K a of the indicator methyl orange is 3.46....Ch. 17 - 17.88 Sketch the titration curve of a weak acid...Ch. 17 - A 200-mL volume of KaOH solution was added to 400...Ch. 17 - 17.90 The of butyric acid (HBut) is 4.7....Ch. 17 - A solution is made by mixing exactly 500 mL of...Ch. 17 - The titration curve shown here represents the...Ch. 17 - Cd ( OH ) 2 is an insoluble compound. It dissolves...Ch. 17 - A student mixes 50 .0 mL of 1 .00 M Ba ( OH ) 2...Ch. 17 - For which of the following reactions is the...Ch. 17 - Water containing Ca 2+ and Mg 2+ ions is called...Ch. 17 - Equal volumes of 0 .12 M AgNO 3 and 0 .14 M ZnCl 2...Ch. 17 - Find the approxite pH range suitable for...Ch. 17 - 17.99 Calculate the solubility (in g/L) of
Ch. 17 - 17.100 A volume of is titrated against a ...Ch. 17 - Prob. 101APCh. 17 - 17.102 When a KI solution was added to a solution...Ch. 17 - Which of the following compounds, when added to...Ch. 17 - The p K a of phenolphthalein is 9.10. Over what pH...Ch. 17 - Solid NaBr is slowly added to a solution that is...Ch. 17 - 17.106 Cacodylic acid is . Us ionization constant...Ch. 17 - Prob. 107APCh. 17 - Prob. 108APCh. 17 - Prob. 109APCh. 17 - CaSO 4 ( K sp = 2.4 × 10 − 5 ) has a larger K sp...Ch. 17 - Describe how you would prepare 1 − L0 .20 M CH 3...Ch. 17 - Phenolphthalein is the common indicator for the...Ch. 17 - Prob. 113APCh. 17 - 17.114 The molar mass of a certain metal...Ch. 17 - Consider the ionization of the following acid-base...Ch. 17 - One way to distinguish a buffer solution with an...Ch. 17 - 17.117 (a) Referring to Figure 17.4. describe how...Ch. 17 - AgNO 3 is added slowly to a solution that contains...Ch. 17 - The follwing diagrams represent solutions of MX,...Ch. 17 - 17.120 A 2.0-L kettle contains 116 g of boiler...Ch. 17 - 17.121 Radiochemical techniques are useful in...Ch. 17 - 17.122 One of the most common antibiotics is...Ch. 17 - 17.123 Barium is a toxic substance that can...Ch. 17 - 17.124 Tris [tris(hydroxymethyl)aminomethane] is a...Ch. 17 - Calcium oxalate is a major component of kidney...Ch. 17 - Histidine is one of the 20 amino acids found in...Ch. 17 - Amino acids are building blocks of proteins. These...Ch. 17 - 17.128 Oil paintings containing lead(II) compounds...Ch. 17 - 17.129 The maximum allowable concentration of ...Ch. 17 - Prob. 130APCh. 17 - When lemon juice is added to tea. the color...Ch. 17 - How many milliliters of 1.0 M NaOH must be added...Ch. 17 - Prob. 133APCh. 17 - Distribution curves show how the fractions of a...Ch. 17 - 17.135 A 1.0-L saturated silver carbonate solution...Ch. 17 - Draw distribution curves for an aqueous carbonic...Ch. 17 - 17.137 Acid-base reactions usually go to...Ch. 17 - Calculate x, the number of molecules of water in...Ch. 17 - Prob. 1SEPPCh. 17 - Aqueous acid reacts with carbonate Jons to produce...Ch. 17 - Aqueous acid reacts with carbonate Jons to produce...Ch. 17 - Prob. 4SEPP
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- Weak base B has a pKb of 6.78 and weak acid HA has a pKa of 5.12. a Which is the stronger base, B or A? b Which is the stronger acid, HA or BH+? c Consider the following reaction: B(aq)+HA(aq)BH+(aq)+A(aq) Based on the information about the acid/base strengths for the species in this reaction, is this reaction favored to proceed more to the right or more to the left? Why? d An aqueous solution is made in which the concentration of weak base B is one half the concentration of its acidic salt, BHCl, where BH+ is the conjugate weak add of B. Calculate the pH of the solution. e An aqueous solution is made in which the concentration of weak acid HA twice the concentration of the sodium salt of the weak acid, NaA. Calculate the pH of the solution. f Assume the conjugate pairs B/BH+ and HA/A are capable of being used as color-based end point indicators in acidbase titrations, where B is the base form indicator and BH is the acid form indicator, and HA is the acid form indicator and A is the base form indicator. Select the indicator pair that would be best to use in each of the following titrations: (1) Titration of a strong acid with a strong base. (i) B/BH+ (ii) HA/A (2) Titration of a weak base with a strong acid. (i) B/BH+ (ii) HA/Aarrow_forwardAn analytical chemist is titrating 93.1 mL of a 0.8600 M solution of butanoic acid (HC,H,CO,) with a 1.100 M solution of KOH. The p K, of butanoic a acid is 4.82. Calculate the pH of the acid solution after the chemist has added 83.4 mL of the KOH solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of KOH solution added. Round your answer to 2 decimal places. pH =arrow_forwardAn analytical chemist Is titrating 150.5 mL of a 0.1400M solution of aniline (CH,NH,) with a 0.4000M solution of HNO,. The p K, of aniline is 9.37. Calculate the pH of the base solutlon after the chemist has added 17.1 mL of the HNO, solution to It. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HNO, solution added. 3. Round your answer to 2 decimal places. pH = || Explanation Check 2021 McGraw-Hill Education. All Rights Reserved. Terms of Use Privacy Accessibilit hp -> Ce esc & @ #3 $4 8. 1 3 4 t y W tabarrow_forward
- An analytical chemist is titrating 216.5 mL of a 0.9400M solution of propionic acid (HC,H,CO,) with a 0.3500M solution of KOH. The p K, of propionic acid is 4.89. Calculate the pH of the acid solution after the chemist has added 622.8 mL of the KOH solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of KOH solution added. Round your answer to 2 decimal places. olo Ar pH = Iarrow_forwardAn analytical chemist is titrating 205.8 mL of a 0.09100M solution of propylamine (C,H,NH, with a 0.1800M solution of HNO2. The p K, of propylamine is 3.46. Calculate the pH of the base solution after the chemist has added 110.6 mL of the HNO, solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HNO, solution added. Round your answer to 2 decimal places. pHarrow_forwardAn analytical chemist is titrating 51.1 mL of a 0.3100M solution of formic acid (H,CO,) with a 0.9300M solution of NaOH. The p K, of formic acid is 3.74. Calculate the pH of the acid solution after the chemist has added 3.76 mL of the NaOH solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of NaOH solution added. Round your answer to 2 decimal places. pH =arrow_forward
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