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Chapter 17 Solutions
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- How to do the mechanism drawn for the reactionarrow_forwardPlease provide the mechanism for this reacitonarrow_forwardQuestion 5: Name the following compound in two ways using side chain and using prefix amine (Common name and IUPAC name both) CH3NH2 CH3CH2NHCH3 CH₂CH₂N(CH3)2 Draw the structure of diethyl methyl amine Question 6. Write the balanced combustion reaction for: a. Hexane b. Propyne c. 2-pentene Question 7: Write the following electrophilic substitution reactions of benzene: Hint: Use notes if you get confused a. Halogenation reaction: b. Nitration reaction : c. Sulphonation reaction: d. Alkylation reaction: e. Aceylation reaction:arrow_forward
- Question 4. Name the following structures ○ CH3-C-N-H H CH3CH2-C-N-H H CH3CH2-C-N-CH3 Harrow_forwardA. Add Water to below compound which 2-methyl 2-butene (addition Reaction) H₂C CH₂ CH, + H₂O-> ? Major product? Minor product? B. Add Bromine to the compound which 2-methyl 2-butene (addition Reaction) CH₂ CH₂ + Br₂→ ? Major product and Minor product both are same in this? C. Add Hydrogen Bromide to the compound which 2-methyl 2-butene (addition Reaction) H,C CH₂ CH₂ + HBr Major product? Minor product? D. Add Hydrogen to the compound which 2-methyl 2-butene (addition Reaction) CH₂ CH₂ + H₂ Major product and Minor product both are same in this?arrow_forward36) Complete the following multi-step reactions showing applications of enolate ions arising from ketones, esters, malonic ester, and keto ester, etc. (30 pts) (1) A NaOH, H₂O+ heat A NaOEt EtO OEt (11) EOH, H+ H. B LDA, H₂O+ -78°C B (i) NaOMe, Et-Br (ii) H₂O+, heat EtOOC (III) COOEt B A (i) NaOEt LiAlH 4-bromo-2-butene H₂O+ (ii) H3O+, heat Write the mechanism for Aldol Condensation (I A or B), and Claisen Condensation (II A).arrow_forward
- 31) Complete two sets of reactions involving (R)-4-methyl-pent-2-ol producing racemic mixture of tertiary alcohols (D) and ketone derivative (C). Illustrate the mechanism of B and C or D. (25 pts) O OH 0 K2Cr2O7 Ph-CH2-Br, Mg, H2SO4 THF, H3O* (A) (D) Racemic mixture TsCl, Py (B) KCN, DMSO Ph-CH2-Br, Mg, THF, H3O+ (C) Mechanism for reactions B and C:arrow_forwardManoharan Mariappan, Ph.D., Dept. of Natur. Sci., NFC, Tallahassee, FL 33) Synthesize the aromatic compound containing para-substituted carbonyl compound starting from benzene. Illustrate the mechanism for reaction A. 1) NU (25 pts) A FeCl B (i) HNO3, H2SO4 (II) Sn, HCl(aq) NH₂ NO₂-D NH₂ (i) MeCO2Me, heat C (ii) K2Cr2O7/H2SO4 D (ii) SOCl2 (iii) 2 Et-NH2 Mechanism for reaction for the nitration of alkyl benzene (B-i): Characterize the product compound arising from the reaction D by IR and IH NMR spectral data: IR data (cm): 'H NMR data: Draw the structure and assign the chemical shift with the spin-splitting.arrow_forwardWrite structural formulas for the major products by doing addition reactions 1. You must add H2 as Pt is catalyst it does not take part in reactions only speed up the process H₂ CH2=CH-CH3 Pt 2. Add HCI break it into H and Cl CH3 HCI 3. Add Br2 only CC14 is catalyst CH3-CH=CH2 B12 CCl4 4. Add water to this and draw major product, H2SO4 is catalyst you have add water H20 in both the reaction below H₂SO4 CH3-CH=CH2 CH3 H2SO4/H₂O CH3-C=CH2 reflux ?arrow_forward
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