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OWLv2 for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 1 term (6 months)
8th Edition
ISBN: 9781305079311
Author: William L. Masterton; Cecile N. Hurley
Publisher: Cengage Learning US
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Chapter 17, Problem 44QAP
Write the equation for the reaction, if any, that occurs when each of the following experiments is performed under standard conditions.
(a) Sulfur is added to mercury.
(b) Manganese dioxide in acidic solution is added to liquid mercury.
(c) Aluminum metal is added to a solution of potassium ions.
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3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
CN
+ En
CN
3) Propagation of uncertainty. Every measurement has uncertainty. In this problem, we'll
evaluate the uncertainty in every step of a titration of potassium hydrogen phthalate (a
common acid used in titrations, abbreviated KHP, formula CsH5KO4) with NaOH of an
unknown concentration.
The calculation that ultimately needs to be carried out is:
concentration NaOH
1000 x mass KHP × purity KHP
molar mass KHP x volume NaOH
Measurements:
a) You use a balance to weigh 0.3992 g of KHP. The uncertainty is ±0.15 mg (0.00015
g).
b) You use a buret to slowly add NaOH to the KHP until it reaches the endpoint. It takes
18.73 mL of NaOH. The uncertainty of the burst is 0.03 mL..
c) The manufacturer states the purity of KHP is 100%±0.05%.
d) Even though we don't think much about them, molar masses have uncertainty as well.
The uncertainty comes from the distribution of isotopes, rather than random
measurement error. The uncertainty in the elements composing KHP are:
a. Carbon:
b. Hydrogen:
±0.0008…
Don't used hand raiting and don't used Ai solution
Chapter 17 Solutions
OWLv2 for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 1 term (6 months)
Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Prob. 3QAPCh. 17 - Balance the following reactions in acid: (a)...Ch. 17 - Write balanced equations for the following...Ch. 17 - Write balanced equations for the following...Ch. 17 - Prob. 7QAPCh. 17 - Write balanced net ionic equations for the...Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Prob. 10QAP
Ch. 17 - Write a balanced chemical equation for the overall...Ch. 17 - Write a balanced net ionic equation for the...Ch. 17 - Draw a diagram for a salt bridge cell for each of...Ch. 17 - Follow the directions in Question 13 for the...Ch. 17 - Consider a voltaic salt bridge cell represented by...Ch. 17 - Consider a salt bridge voltaic cell represented by...Ch. 17 - Consider a salt bridge cell in which the anode is...Ch. 17 - Follow the directions in Question 17 for a salt...Ch. 17 - Prob. 19QAPCh. 17 - Which species in each pair is the stronger...Ch. 17 - Using Table 17.1, arrange the following reducing...Ch. 17 - Use Table 17.1 to arrange the following oxidizing...Ch. 17 - Consider the following species. Cr3+ Hg(l) H2...Ch. 17 - Follow the directions of Question 23 for the...Ch. 17 - For the following half-reactions, answer these...Ch. 17 - For the following half-reactions, answer the...Ch. 17 - Use Table 17.1 to select (a) a reducing agent in...Ch. 17 - Use Table 17.1 to select (a) an oxidizing agent in...Ch. 17 - Calculate E° for the following voltaic cells: (a)...Ch. 17 - Calculate E° for the following voltaic cells: (a)...Ch. 17 - Using Table 17.1, calculate E° for the reaction...Ch. 17 - Using Table 17.1, calculate E° for the reaction...Ch. 17 - Calculate E° for the following cells: (a)...Ch. 17 - Calculate E° for the following cells: (a)...Ch. 17 - Suppose Ered for Ag+Ag were set equal to zero...Ch. 17 - Suppose Ered for H+H2 were taken to be 0.300 V...Ch. 17 - Which of the following reactions is/are...Ch. 17 - Which of the following reactions is(are)...Ch. 17 - Use the following half-equations to write three...Ch. 17 - Follow the directions of Question 39 for the...Ch. 17 - Use Table 17.1 to answer the following questions:...Ch. 17 - Use Table 17.1 to answer the following questions....Ch. 17 - Write the equation for the reaction, if any, that...Ch. 17 - Write the equation for the reaction, if any, that...Ch. 17 - Prob. 45QAPCh. 17 - Prob. 46QAPCh. 17 - Use Table 17.1 to predict what reaction, if any,...Ch. 17 - Use Table 17.1 to predict what reaction, if any,...Ch. 17 - Consider a cell reaction at 25°C where n=2 . Fill...Ch. 17 - Consider a cell reaction at 25°C where n=4 . Fill...Ch. 17 - For a certain cell, G=25.0 kJ. Calculate E° if n...Ch. 17 - For a certain cell, E=1.08 V. Calculate G° if n is...Ch. 17 - Calculate E°, G°, and K at 25°C for the reaction...Ch. 17 - Calculate E°, G°, and K at 25°C for the reaction...Ch. 17 - Calculate G° at 25°C for each of the reactions...Ch. 17 - Calculate G° at 25°C for each of the reactions...Ch. 17 - Calculate K at 25°C for each of the reactions...Ch. 17 - Calculate K at 25°C for each of the reactions...Ch. 17 - Prob. 59QAPCh. 17 - Use Table 17.1 to find Kffor AuCl4- (aq) at 25°C.Ch. 17 - Prob. 61QAPCh. 17 - What is E° at 25°C for the following reaction?...Ch. 17 - Consider a voltaic cell at 25°C in which the...Ch. 17 - Consider a voltaic cell at 25°C in which the...Ch. 17 - Consider a voltaic cell in which the following...Ch. 17 - Consider a voltaic cell in which the following...Ch. 17 - Calculate the voltages of the following cells at...Ch. 17 - Calculate the voltages of the following cells at...Ch. 17 - Consider the reaction...Ch. 17 - Consider the reaction at 25°C:...Ch. 17 - Complete the following cell notation....Ch. 17 - Complete the following cell notation....Ch. 17 - Consider the reaction below at 25°C:...Ch. 17 - Consider the reaction low at 25°C:...Ch. 17 - Consider a cell in which the reaction is...Ch. 17 - Consider a cell in which the reaction is...Ch. 17 - An electrolytic cell produces aluminum from Al2O3...Ch. 17 - Prob. 78QAPCh. 17 - A solution containing a metal ion (M2+(aq)) is...Ch. 17 - A solution containing a metal ion (M2+(aq)) is...Ch. 17 - A baby's spoon with an area of 6.25 cm2 is plated...Ch. 17 - A metallurgist wants to gold-plate an object with...Ch. 17 - A lead storage battery delivers a current of 6.00...Ch. 17 - Calcium metal can be obtained by the direct...Ch. 17 - Given the following data:...Ch. 17 - In a nickel-cadmium battery (Nicad), cadmium is...Ch. 17 - Hydrogen gas is produced when water is...Ch. 17 - Consider the electrolysis of NiCl2 to Ni(s) and...Ch. 17 - An electrolysis experiment is performed to...Ch. 17 - Prob. 90QAPCh. 17 - Prob. 91QAPCh. 17 - Prob. 92QAPCh. 17 - Atomic masses can be determined by electrolysis....Ch. 17 - Consider the following reaction at 25°C:...Ch. 17 - Given the standard reduction potential for...Ch. 17 - Choose the figure that best represents the results...Ch. 17 - For the cell: Cr|Cr3+Co2+|Co E° is 0.46 V. The...Ch. 17 - Which of the changes below will increase the...Ch. 17 - The standard potential for the reduction of AgSCN...Ch. 17 - Consider the following standard reduction...Ch. 17 - Use Table 17.1 to answer the following questions....Ch. 17 - Consider three metals, X, Y, and Z, and their...Ch. 17 - An alloy made up of tin and copper is prepared by...Ch. 17 - In a fully charged lead storage battery, the...Ch. 17 - Consider a voltaic cell in which the following...Ch. 17 - In biological systems, acetate ion is converted to...Ch. 17 - Consider the cell Pt|H2|H+H+|H2|Pt In the anode...Ch. 17 - Prob. 108QAPCh. 17 - Prob. 109QAP
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