(a) Interpretation: The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents. Cr or Cd Concept introduction: Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction . Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Question

29. Use frontier orbital analysis (HOMO-LUMO interactions) to decide whether the following dimerization is 1) thermally allowed or forbidden and 2) photochemically allowed or forbidden. +

Answer 1

Question

Chapter 17, Problem 19QAP

Interpretation Introduction

(a)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

Cr or Cd

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(b)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

I- or Br-

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(c)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

OH- or NO₂ - (basic solution)

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(d)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

NO in acidic solution or NO in basic solution

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

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Answer 2

Question

Chapter 17, Problem 19QAP

Interpretation Introduction

(a)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

Cr or Cd

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(b)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

I- or Br-

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(c)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

OH- or NO₂ - (basic solution)

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(d)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

NO in acidic solution or NO in basic solution

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

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Answer 3

Question

Chapter 17, Problem 19QAP

Interpretation Introduction

(a)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

Cr or Cd

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(b)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

I- or Br-

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(c)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

OH- or NO₂ - (basic solution)

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(d)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

NO in acidic solution or NO in basic solution

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

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Answer 4

Question

Chapter 17, Problem 19QAP

Interpretation Introduction

(a)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

Cr or Cd

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(b)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

I- or Br-

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(c)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

OH- or NO₂ - (basic solution)

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(d)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

NO in acidic solution or NO in basic solution

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

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Answer 5

Chapter 17, Problem 19QAP

Interpretation Introduction

(a)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

Cr or Cd

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(b)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

I- or Br-

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(c)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

OH- or NO₂ - (basic solution)

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Interpretation Introduction

(d)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

NO in acidic solution or NO in basic solution

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 6

Chapter 17, Problem 19QAP

Interpretation Introduction

(a)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

Cr or Cd

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 7

Chapter 17, Problem 19QAP

Interpretation Introduction

(a)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

Cr or Cd

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

I- or Br-

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

I- or Br-

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

OH- or NO₂ - (basic solution)

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

OH- or NO₂ - (basic solution)

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

NO in acidic solution or NO in basic solution

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The stronger oxidizing agent needs to be identified between the following pair of oxidizing agents.

NO in acidic solution or NO in basic solution

Concept introduction:

Oxidizing agent is the species which oxides others and itself gets reduced in a chemical reaction. Thus, the more positive the standard potential more strongly the species can undergo reduction and act as a strong oxidizing agent.

Answer 14

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Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Prob. 3QAP Ch. 17 - Balance the following reactions in acid: (a)...Ch. 17 - Write balanced equations for the following...Ch. 17 - Write balanced equations for the following...Ch. 17 - Prob. 7QAP Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Prob. 10QAP

Solution Summary: The author explains that the stronger oxidizing agent needs to be identified between the following two pairs: Cr, Cd, and Br.

Chapter 17 Solutions