GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
10th Edition
ISBN: 9781260699227
Author: Denniston
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 17, Problem 17.89QP
Interpretation Introduction
Interpretation:
The terms of good and bad cholesterol meaning should be provided.
Concept Introduction:
Cholesterol is a fatty substance lipid, which is essential to healthy life. It is found the brain, nervous tissue, skin and adrenal glands. It has three main functions within the body.
Cholesterol is manufactured mainly in the liver but is also present in saturated fat found in meat and dairy products and many processed foods. Excess saturated fat in the diet increase blood cholesterol.
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Consider the reaction below to answer the following questions:
847
Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate.
H₁C
0
H
0
IL
유
||
OCH2CH3
1. NaOEt, EtOH C
2. H₂O
H3C
CH₂
Cold not tobizmo. S
OCH2CH3
A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and
draw all intermediate structures.
B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents
and structures for all intermediates in this preparation.
C. Give the structures of the ester precursors for the following Claisen condensation product and
formulate the reaction.
ou
OEL
A.
What is the correct structure for a-D-glucopyranose?
CH₂OH
a
HO
HO-
OH
b
HO
HO-
OH
HOH₂C
OH
OH
OH
CH₂OH
HO
C.
HO
HO-
OH
OH
CH₂OH
OH
OH
B. Draw structures for the products you would expect to obtain from reaction of B-D-galactopyranose
with each of the following reagents. Be sure to include all relevant stereochemistry. [FOUR only]
A. CH, Ag₂O
B. warm dilute HNO3
C. (CH3CO)20, pryridine
D. NaBH in H₂O
E. CH₂OH, HCI
F. Br₂, H₂O
HO
CH₂OH
HO-
OH
OH
B-D-galactopyranose
Give the major organic product(s) for each of the following reactions or reaction sequences.
CH₂CN
5% NaOEt, EIOH
سجد سی . بلی
H
1. NaOCH, CH,OH
CH3
OCH3
2 H₂O*
Chapter 17 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
Ch. 17.3 - Write a complete equation for the acid hydrolysis...Ch. 17.3 - Prob. 17.6PPCh. 17.3 - Prob. 17.3QCh. 17.3 - Prob. 17.4QCh. 17.3 - Prob. 17.5QCh. 17.3 - Prob. 17.6QCh. 17.3 - Prob. 17.7QCh. 17.3 - Prob. 17.8QCh. 17.3 - Prob. 17.9QCh. 17.3 - Prob. 17.10Q
Ch. 17.3 - Prob. 17.11QCh. 17.3 - Prob. 17.12QCh. 17.4 - Prob. 17.13QCh. 17.4 - What is meant by the term fused ring?
Ch. 17.5 - Prob. 17.15QCh. 17.5 - Prob. 17.16QCh. 17 - Prob. 17.17QPCh. 17 - List the biological functions of lipids.
Ch. 17 - In terms of solubility, explain why a diet that...Ch. 17 - Why are lipids (triglycerides) such an efficient...Ch. 17 - What is the difference between a saturated and an...Ch. 17 - Prob. 17.22QPCh. 17 - As the length of the hydrocarbon chain of...Ch. 17 - As the number of carbon-carbon double bonds in...Ch. 17 - Explain the relationship between fatty acid chain...Ch. 17 - Explain the relationship you described in the...Ch. 17 - Prob. 17.27QPCh. 17 - Prob. 17.28QPCh. 17 - Prob. 17.29QPCh. 17 - Prob. 17.30QPCh. 17 - Write an equation for the esterification of...Ch. 17 - Prob. 17.32QPCh. 17 - Prob. 17.33QPCh. 17 - Write an equation for the acid hydrolysis of a...Ch. 17 - Prob. 17.35QPCh. 17 - Prob. 17.36QPCh. 17 - Using line formulas, write an equation for the...Ch. 17 - Using line formulas, write an equation for the...Ch. 17 - Write an equation for the base-catalyzed...Ch. 17 - Prob. 17.40QPCh. 17 - Write an equation for the esterification of...Ch. 17 - Prob. 17.42QPCh. 17 - Prob. 17.43QPCh. 17 - Prob. 17.44QPCh. 17 - Prob. 17.45QPCh. 17 - Prob. 17.46QPCh. 17 - Prob. 17.47QPCh. 17 - Prob. 17.48QPCh. 17 - What do the terms omega-3 and omega-6 indicate...Ch. 17 - Prob. 17.50QPCh. 17 - Prob. 17.51QPCh. 17 - Prob. 17.52QPCh. 17 - Prob. 17.53QPCh. 17 - Prob. 17.54QPCh. 17 - Prob. 17.55QPCh. 17 - Prob. 17.56QPCh. 17 - Prob. 17.57QPCh. 17 - Define the term phosphatidate.
Ch. 17 - Prob. 17.59QPCh. 17 - Prob. 17.60QPCh. 17 - Prob. 17.61QPCh. 17 - Prob. 17.62QPCh. 17 - Prob. 17.63QPCh. 17 - Prob. 17.64QPCh. 17 - Prob. 17.65QPCh. 17 - Prob. 17.66QPCh. 17 - Prob. 17.67QPCh. 17 - Prob. 17.68QPCh. 17 - Prob. 17.69QPCh. 17 - Prob. 17.70QPCh. 17 - Prob. 17.71QPCh. 17 - Prob. 17.72QPCh. 17 - Prob. 17.75QPCh. 17 - Prob. 17.78QPCh. 17 - Prob. 17.79QPCh. 17 - Prob. 17.80QPCh. 17 - Prob. 17.85QPCh. 17 - Prob. 17.86QPCh. 17 - Prob. 17.87QPCh. 17 - Prob. 17.88QPCh. 17 - Prob. 17.89QPCh. 17 - Prob. 17.90QPCh. 17 - Prob. 17.91QPCh. 17 - Prob. 17.92QPCh. 17 - Prob. 17.93QPCh. 17 - Prob. 17.94QPCh. 17 - Prob. 17.95QPCh. 17 - Prob. 17.96QPCh. 17 - Prob. 17.97QPCh. 17 - Prob. 17.98QPCh. 17 - Prob. 17.99QPCh. 17 - Prob. 17.100QPCh. 17 - Prob. 17.101QPCh. 17 - Prob. 17.103QPCh. 17 - What is the function of unsaturation in the...Ch. 17 - Prob. 1MCPCh. 17 - Prob. 2MCPCh. 17 - Prob. 3MCPCh. 17 - Prob. 5MCPCh. 17 - Prob. 6MCPCh. 17 - Prob. 7MCPCh. 17 - “Cholesterol is bad and should be eliminated from...Ch. 17 - Prob. 9MCPCh. 17 - When a plant becomes cold-adapted, the composition...
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