PKG ORGANIC CHEMISTRY
PKG ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259963667
Author: SMITH
Publisher: MCG
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Chapter 17, Problem 17.53P

How many 13 C NMR signals does each compound exhibit?

a. Chapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  1 bChapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  2. c. Chapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  3 d. Chapter 17, Problem 17.53P, 17.53 How many  signals does each compound exhibit?
a. 	b.	c. 	d. 
 , example  4

Expert Solution
Check Mark
Interpretation Introduction

(a)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is five.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains five different types of carbon atoms as follows.

PKG ORGANIC CHEMISTRY, Chapter 17, Problem 17.53P , additional homework tip  1

Figure 1

Thus, the number of 13CNMR signals exhibited by the given compound is five.

Conclusion

The number of 13CNMR signals exhibited by the given compound is five.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is nine.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains nine different types of carbon atoms as follows.

PKG ORGANIC CHEMISTRY, Chapter 17, Problem 17.53P , additional homework tip  2

Figure 2

Thus, the number of 13CNMR signals exhibited by the given compound is nine.

Conclusion

The number of 13CNMR signals exhibited by the given compound is nine.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is three.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains three different types of carbon atoms as follows.

PKG ORGANIC CHEMISTRY, Chapter 17, Problem 17.53P , additional homework tip  3

Figure 3

Thus, the number of 13CNMR signals exhibited by the given compound is three.

Conclusion

The number of 13CNMR signals exhibited by the given compound is three.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation: The number of 13CNMR signals exhibited by the given compound is to be predicted.

Concept introduction: The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

Answer to Problem 17.53P

The number of 13CNMR signals exhibited by the given compound is four.

Explanation of Solution

The 13CNMR spectroscopy is an important tool for the elucidation of organic structures of molecules. The physical basis for it is same as for 1HNMR. 13CNMR spectrum is comparatively easier to analyze than 1HNMR. Each type of carbon atom appears as one signal in 13CNMR spectrum.

The given compound contains four different types of carbon atoms as follows.

PKG ORGANIC CHEMISTRY, Chapter 17, Problem 17.53P , additional homework tip  4

Figure 4

Thus, the number of 13CNMR signals exhibited by the given compound is four.

Conclusion

The number of 13CNMR signals exhibited by the given compound is four.

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Chapter 17 Solutions

PKG ORGANIC CHEMISTRY

Ch. 17 - Prob. 17.11PCh. 17 - Prob. 17.12PCh. 17 - Prob. 17.13PCh. 17 - Problem 17.14 Januvia, the trade name for...Ch. 17 - Prob. 17.15PCh. 17 - Problem 17.16 Rank the following compounds in...Ch. 17 - Problem 17.17 Draw the seven resonance structures...Ch. 17 - Prob. 17.18PCh. 17 - Prob. 17.19PCh. 17 - Prob. 17.20PCh. 17 - Prob. 17.21PCh. 17 - Problem 17.22 How many NMR signals does ...Ch. 17 - 17.23 Name each compound and state how many lines...Ch. 17 - Prob. 17.24PCh. 17 - Prob. 17.25PCh. 17 - Prob. 17.26PCh. 17 - 17.27 Give the IUPAC name for each compounds. a....Ch. 17 - 17.28 Draw a structure corresponding to each...Ch. 17 - 17.29 a. Draw the 14 constitutional isomers of...Ch. 17 - Prob. 17.30PCh. 17 - Prob. 17.31PCh. 17 - Prob. 17.32PCh. 17 - 17.33 Label each compound as aromatic,...Ch. 17 - Prob. 17.34PCh. 17 - 17.35 Pentalene, azulene, and heptalene are...Ch. 17 - 17.36 The purine heterocycle occurs commonly in...Ch. 17 - Prob. 17.37PCh. 17 - 17.38 How many electrons does C contain? How...Ch. 17 - Prob. 17.39PCh. 17 - 17.40 Explain the observed rate of reactivity of...Ch. 17 - 17.41 Draw a stepwise mechanism for the following...Ch. 17 - Prob. 17.42PCh. 17 - 17.43 Draw additional resonance structures for...Ch. 17 - Prob. 17.44PCh. 17 - Prob. 17.45PCh. 17 - 17.46 Which compound in each pair is the stronger...Ch. 17 - 17.47 Treatment of indene with forms its...Ch. 17 - Prob. 17.48PCh. 17 - 17.49 Draw the conjugate bases of pyrrole and...Ch. 17 - 17.50 a. Explain why protonation of pyrrole occurs...Ch. 17 - Prob. 17.51PCh. 17 - Prob. 17.52PCh. 17 - 17.53 How many signals does each compound...Ch. 17 - 17.54 Which of the diethylbenzene isomers (ortho,...Ch. 17 - 17.55 Propose a structure consistent with each...Ch. 17 - 17.56 Propose a structure consistent with each...Ch. 17 - 17.57 Thymol (molecular formula ) is the major...Ch. 17 - 17.58 You have a sample of a compound of molecular...Ch. 17 - 17.59 Explain why tetrahydrofuran has a higher...Ch. 17 - 17.60 Rizatriptan (trade name Maxalt) is a...Ch. 17 - 17.61 Zolpidem (trade name Ambien) promotes the...Ch. 17 - 17.62 Answer the following questions about...Ch. 17 - 17.63 Stanozolol is an anabolic steroid that...Ch. 17 - Prob. 17.64PCh. 17 - 17.65 Use the observed data to decide whether C...Ch. 17 - Prob. 17.66PCh. 17 - Prob. 17.67PCh. 17 - Prob. 17.68PCh. 17 - 17.69 Although benzene itself absorbs at in its ...
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