Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393600681
Author: Gilbert
Publisher: W. W. Norton & Company
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Chapter 17, Problem 17.49QA
Interpretation Introduction
To find:
The value of the equilibrium constantfor the given reaction at
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
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F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 17 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 17 - Prob. 17.1VPCh. 17 - Prob. 17.2VPCh. 17 - Prob. 17.3VPCh. 17 - Prob. 17.4VPCh. 17 - Prob. 17.5VPCh. 17 - Prob. 17.6VPCh. 17 - Prob. 17.7VPCh. 17 - Prob. 17.8VPCh. 17 - Prob. 17.9VPCh. 17 - Prob. 17.10VP
Ch. 17 - Prob. 17.11QACh. 17 - Prob. 17.12QACh. 17 - Prob. 17.13QACh. 17 - Prob. 17.14QACh. 17 - Prob. 17.15QACh. 17 - Prob. 17.16QACh. 17 - Prob. 17.17QACh. 17 - Prob. 17.18QACh. 17 - Prob. 17.19QACh. 17 - Prob. 17.20QACh. 17 - Prob. 17.21QACh. 17 - Prob. 17.22QACh. 17 - Prob. 17.23QACh. 17 - Prob. 17.24QACh. 17 - Prob. 17.25QACh. 17 - Prob. 17.26QACh. 17 - Prob. 17.27QACh. 17 - Prob. 17.28QACh. 17 - Prob. 17.29QACh. 17 - Prob. 17.30QACh. 17 - Prob. 17.31QACh. 17 - Prob. 17.32QACh. 17 - Prob. 17.33QACh. 17 - Prob. 17.34QACh. 17 - Prob. 17.35QACh. 17 - Prob. 17.36QACh. 17 - Prob. 17.37QACh. 17 - Prob. 17.38QACh. 17 - Prob. 17.39QACh. 17 - Prob. 17.40QACh. 17 - Prob. 17.41QACh. 17 - Prob. 17.42QACh. 17 - Prob. 17.43QACh. 17 - Prob. 17.44QACh. 17 - Prob. 17.45QACh. 17 - Prob. 17.46QACh. 17 - Prob. 17.47QACh. 17 - Prob. 17.48QACh. 17 - Prob. 17.49QACh. 17 - Prob. 17.50QACh. 17 - Prob. 17.51QACh. 17 - Prob. 17.52QACh. 17 - Prob. 17.53QACh. 17 - Prob. 17.54QACh. 17 - Prob. 17.55QACh. 17 - Prob. 17.56QACh. 17 - Prob. 17.57QACh. 17 - Prob. 17.58QACh. 17 - Prob. 17.59QACh. 17 - Prob. 17.60QACh. 17 - Prob. 17.61QACh. 17 - Prob. 17.62QACh. 17 - Prob. 17.63QACh. 17 - Prob. 17.64QACh. 17 - Prob. 17.65QACh. 17 - Prob. 17.66QACh. 17 - Prob. 17.67QACh. 17 - Prob. 17.68QACh. 17 - Prob. 17.69QACh. 17 - Prob. 17.70QACh. 17 - Prob. 17.71QACh. 17 - Prob. 17.72QACh. 17 - Prob. 17.73QACh. 17 - Prob. 17.74QACh. 17 - Prob. 17.75QACh. 17 - Prob. 17.76QACh. 17 - Prob. 17.77QACh. 17 - Prob. 17.78QACh. 17 - Prob. 17.79QACh. 17 - Prob. 17.80QACh. 17 - Prob. 17.81QACh. 17 - Prob. 17.82QACh. 17 - Prob. 17.83QACh. 17 - Prob. 17.84QACh. 17 - Prob. 17.85QACh. 17 - Prob. 17.86QACh. 17 - Prob. 17.87QACh. 17 - Prob. 17.88QACh. 17 - Prob. 17.89QACh. 17 - Prob. 17.90QACh. 17 - Prob. 17.91QACh. 17 - Prob. 17.92QACh. 17 - Prob. 17.93QACh. 17 - Prob. 17.94QACh. 17 - Prob. 17.95QACh. 17 - Prob. 17.96QACh. 17 - Prob. 17.97QACh. 17 - Prob. 17.98QACh. 17 - Prob. 17.99QACh. 17 - Prob. 17.100QACh. 17 - Prob. 17.101QACh. 17 - Prob. 17.102QA
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Similar questions
- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
- QUESTION 3: Provide the synthetic steps that convert the starting material into the product (no mechanism required). HO OH NH CH3 multiple steps 요요 H3Carrow_forwardQ6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.arrow_forwardQ3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2 reaction rate. a) CI Cl فيكم H3C-Cl A B C D Br Br b) A B C Br H3C-Br Darrow_forward
- Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forwardSuppose the rate of evaporation in a hot, dry region is 1.76 meters per year, and the seawater there has a salinity of 35 ‰. Assuming a 93% yield, how much salt (NaCl) can be harvested each year from 1 km2 of solar evaporation ponds that use this seawater as a source?arrow_forwardhelparrow_forward
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