EP FUND.OF GENERAL,ORG...-MOD.MASTERING
8th Edition
ISBN: 9780134326061
Author: McMurry
Publisher: PEARSON CO
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Question
Chapter 17, Problem 17.39AP
(a)
Interpretation Introduction
Interpretation:
The structure of benzoic acid has to be drawn.
Concept Introduction:
In chemistry Structure is the arrangement of
Benzoic acid: Benzoic acid is an organic compound with one
(b)
Interpretation Introduction
Interpretation:
The structure major organic species formed when benzoic acid reacts with
Concept Introduction:
Carboxylic acid: One
Carboxylic acid salt: It is an ionic compound having a carboxylate acid anion and a cation. It is formed when a carboxylic acid and a strong base reacts giving water.
Salt of carboxylic acids are written as name of cation in prefix and base name with “-oate” suffix.
(c)
Interpretation Introduction
Interpretation:
The structure major organic species formed when
Concept Introduction:
Carboxylic acid: One
Carboxylic acid salt: It is an ionic compound having a carboxylate acid anion and a cation. It is formed when a carboxylic acid and a strong base reacts giving water.
When a carboxylic acid salt reacts with a strong acid the corresponding carboxylic acid and a salt is formed.
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Consider the Ramachandran plot shown to answer both questions.
fr (degrees)
180
120
8280
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-60
Which observation most likely describes part of an observed a helix?
p=-59 degrees; y = +150 degrees; many Ser residues
qp=-140 degrees; w +130 degrees; many Val residues
qp=-57 degrees; y = -47 degrees; many Pro residues
qp=-60 degrees; y = -47 degrees; many Ala residues
p = +60 degrees; y = +40 degrees; many Gly residues
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qp=-59 degrees; y = -49 degrees; many Ala residues
qp = +60 degrees; w = +60 degrees; many Gly residues
qp=-120 degrees; y = +120 degrees; many Tyr residues
☐ ☐
qp=-139 degrees; y = +135 degrees; many Val residues
op=-51 degrees; w+153 degrees; many Gly and Pro…
Please give an intuitive explanation of the difference, if any, between toxicokinetics and pharmacokinetics.
A protein biochemist attempted to determine the amino acid sequence of a decapeptide. The results from the trypsin,
chymotrypsin, and cyanogen bromide treatments are shown:
⚫ Trypsin digestion gave two fragments with multiple residues (not in order):
• T1: Ala, Arg, Phe, Gly, Thr, Trp, Tyr
o T2: Lys, Met, Val
Chymotrypsin digestion gave four fragments with multiple residues (not in order):
• CT1: Ala, Phe
• CT2: Thr, Trp
• CT3: Lys, Met, Tyr, Val
。 CT4: Arg, Gly
⚫ Treatment with cyanogen bromide yielded a single amino acid, methionine, and a nonapeptide.
What is a possible sequence of the decapeptide? Use three-letter abbreviations in your answer, and add a dash between
each residue.
Chapter 17 Solutions
EP FUND.OF GENERAL,ORG...-MOD.MASTERING
Ch. 17.1 - Identify the following molecules as a carboxylic...Ch. 17.1 - Prob. 17.2PCh. 17.1 - Prob. 17.3PCh. 17.1 - Prob. 17.4PCh. 17.1 - Prob. 17.5PCh. 17.1 - Prob. 17.6PCh. 17.1 - In the following pairs of compounds, which would...Ch. 17.1 - Write both condensed and line structures for (a)...Ch. 17.1 - Prob. 17.9PCh. 17.1 - Draw structures corresponding to these names: (a)...
Ch. 17.1 - Prob. 17.11PCh. 17.1 - Prob. 17.12PCh. 17.1 - Prob. 17.13KCPCh. 17.2 - Salsalate, which is an ester formed by the...Ch. 17.2 - Prob. 17.2CIAPCh. 17.2 - Prob. 17.3CIAPCh. 17.2 - Prob. 17.14PCh. 17.2 - Prob. 17.15PCh. 17.2 - Prob. 17.16PCh. 17.3 - Prob. 17.17PCh. 17.3 - Raspberry oil contains an ester that is made by...Ch. 17.3 - Prob. 17.19PCh. 17.3 - Prob. 17.20PCh. 17.3 - Prob. 17.21PCh. 17.4 - If a bottle of aspirin tablets has the aroma of...Ch. 17.4 - Prob. 17.23PCh. 17.4 - What carboxylic acids and amines result from...Ch. 17.5 - Prob. 17.25PCh. 17.5 - Prob. 17.26KCPCh. 17.6 - Prob. 17.27PCh. 17.6 - Prob. 17.28PCh. 17.6 - Prob. 17.4CIAPCh. 17.6 - Prob. 17.5CIAPCh. 17.6 - Prob. 17.29PCh. 17 - Prob. 17.30UKCCh. 17 - Prob. 17.31UKCCh. 17 - One phosphorylated form of glycerate is...Ch. 17 - Prob. 17.33UKCCh. 17 - Prob. 17.34UKCCh. 17 - Prob. 17.35UKCCh. 17 - Prob. 17.36UKCCh. 17 - For the following compounds, give the systematic...Ch. 17 - Write the equation for the ionization of hexanoic...Ch. 17 - Prob. 17.39APCh. 17 - Prob. 17.40APCh. 17 - Prob. 17.41APCh. 17 - Give systematic names for the following carboxylic...Ch. 17 - Give systematic names for the following carboxylic...Ch. 17 - Prob. 17.44APCh. 17 - Prob. 17.45APCh. 17 - Draw structures corresponding to the following...Ch. 17 - Draw structures corresponding to the following...Ch. 17 - Malic acid, a dicarboxylic acid found in apples,...Ch. 17 - Prob. 17.49APCh. 17 - Prob. 17.50APCh. 17 - Prob. 17.51APCh. 17 - Prob. 17.52APCh. 17 - Prob. 17.53APCh. 17 - Give systematic names for the following structures...Ch. 17 - Give systematic names for the following structures...Ch. 17 - Prob. 17.56APCh. 17 - Prob. 17.57APCh. 17 - Give systematic names for the following structures...Ch. 17 - Give systematic names for the following structures...Ch. 17 - Prob. 17.60APCh. 17 - What compounds are produced from hydrolysis of...Ch. 17 - Procaine, a local anesthetic whose hydrochloride...Ch. 17 - Prob. 17.63APCh. 17 - Lactones are cyclic esters in which the carboxylic...Ch. 17 - When both the carboxylic acid and the amine are in...Ch. 17 - LSD (lysergic acid diethylamide), a semisynthetic...Ch. 17 - Prob. 17.67APCh. 17 - Prob. 17.68APCh. 17 - Prob. 17.69APCh. 17 - Prob. 17.70APCh. 17 - Prob. 17.71APCh. 17 - Prob. 17.72APCh. 17 - Prob. 17.73APCh. 17 - Prob. 17.74APCh. 17 - Prob. 17.75APCh. 17 - Three amide isomers, N,N-dimethylformamide,...Ch. 17 - Prob. 17.77CPCh. 17 - Prob. 17.78CPCh. 17 - Mention at least two simple chemical tests by...Ch. 17 - Prob. 17.80CPCh. 17 - Name the following compounds.Ch. 17 - Each of the following materials has an ester that...Ch. 17 - Prob. 17.83GPCh. 17 - Prob. 17.84GP
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