ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 17, Problem 17.29P
a. Draw the 14 constitutional isomers of molecular formula
b. Name all compounds that contain a trisubstituted benzene ring.
c. For which compound(s) are stereoisomers possible? Draw all possible stereoisomers.
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a. Draw the 14 constitutional isomers of molecular formula C8H9Cl that contain a benzene ring.b. Name all compounds that contain a trisubstituted benzene ring.c. For which compound(s) are stereoisomers possible? Draw all possible stereoisomers.
1a. How many stereogenic centers are present 1c. Draw a three-dimensional structure of a
in the structure below? Indicate them with
asterisk(s). How many stereoisomers
stereoisomers are
possible?
chiral compound with the molecular formula
of C4H4Cl₂ that does not have a stereogenic
carbon. In addition, draw the enantiomer of
this compound.
Number of stereogenic centers:
Number of stereoisomers possible:
1b. Draw one of the two most stable
stereoisomers of the compound in 1a using a
planar structure with wedges and dashes. Now
draw it in its preferred chair conformation.
1d. Draw two meso compounds with the
molecular formula of C7H14.
Part D. Do the two structures A and B of each pair drawn below represent the same molecule,
constitutional isomers, or stereoisomers? If A and B are stereoisomers, further classify them as
enantiomers or diastereomers.
H3C
Structure A
H3C
HO
H3C
H3C
Br
T
H
H3C
H
HO
H3CC
H
C
Br
HC
H
H
H
H
CH₂Br
CH₂CH3
H
CH₂CH3
CH₂OH
OH
H HO
G
G
H HO
H HO
G
CH3
CH3
CH3
Br
Hallo
H
H3C
H
Structure B
H3C
CH3
Br
WING
H
Br
HOCH₂
CH3
CH3
HO
H
CH₂OH
H
CH₂CH3
H
CH₂CH3
H
H
H
H
H
H
Gim
CH3 H
OH
"H
·GII.
CH3
HO.
OH
OH
CH3
CH3
OH
Relationship of A and B
Chapter 17 Solutions
ORGANIC CHEMISTRY
Ch. 17 - Prob. 17.1PCh. 17 - Problem 17.2 What orbitals are used to form the...Ch. 17 - Problem-17.3. Give the IUPAC name for each...Ch. 17 - Prob. 17.4PCh. 17 - Problem-17.5 What is the structure of propofol,...Ch. 17 - Problem 17.6 What is the structure of a compound...Ch. 17 - Problem 17.7 How many NMR signals does each...Ch. 17 - Prob. 17.8PCh. 17 - Prob. 17.9PCh. 17 - Prob. 17.10P
Ch. 17 - Prob. 17.11PCh. 17 - Prob. 17.12PCh. 17 - Prob. 17.13PCh. 17 - Problem 17.14 Januvia, the trade name for...Ch. 17 - Prob. 17.15PCh. 17 - Problem 17.16 Rank the following compounds in...Ch. 17 - Problem 17.17 Draw the seven resonance structures...Ch. 17 - Prob. 17.18PCh. 17 - Prob. 17.19PCh. 17 - Prob. 17.20PCh. 17 - Prob. 17.21PCh. 17 - Problem 17.22 How many NMR signals does ...Ch. 17 - 17.23 Name each compound and state how many lines...Ch. 17 - Prob. 17.24PCh. 17 - Prob. 17.25PCh. 17 - Prob. 17.26PCh. 17 - 17.27 Give the IUPAC name for each compounds.
a....Ch. 17 - 17.28 Draw a structure corresponding to each...Ch. 17 - 17.29 a. Draw the 14 constitutional isomers of...Ch. 17 - Prob. 17.30PCh. 17 - Prob. 17.31PCh. 17 - Prob. 17.32PCh. 17 - 17.33 Label each compound as aromatic,...Ch. 17 - Prob. 17.34PCh. 17 - 17.35 Pentalene, azulene, and heptalene are...Ch. 17 - 17.36 The purine heterocycle occurs commonly in...Ch. 17 - Prob. 17.37PCh. 17 - 17.38
How many electrons does C contain?
How...Ch. 17 - Prob. 17.39PCh. 17 - 17.40 Explain the observed rate of reactivity of...Ch. 17 - 17.41 Draw a stepwise mechanism for the following...Ch. 17 - Prob. 17.42PCh. 17 - 17.43 Draw additional resonance structures for...Ch. 17 - Prob. 17.44PCh. 17 - Prob. 17.45PCh. 17 - 17.46 Which compound in each pair is the stronger...Ch. 17 - 17.47 Treatment of indene with forms its...Ch. 17 - Prob. 17.48PCh. 17 - 17.49 Draw the conjugate bases of pyrrole and...Ch. 17 - 17.50 a. Explain why protonation of pyrrole occurs...Ch. 17 - Prob. 17.51PCh. 17 - Prob. 17.52PCh. 17 - 17.53 How many signals does each compound...Ch. 17 - 17.54 Which of the diethylbenzene isomers (ortho,...Ch. 17 - 17.55 Propose a structure consistent with each...Ch. 17 - 17.56 Propose a structure consistent with each...Ch. 17 - 17.57 Thymol (molecular formula ) is the major...Ch. 17 - 17.58 You have a sample of a compound of molecular...Ch. 17 - 17.59 Explain why tetrahydrofuran has a higher...Ch. 17 - 17.60 Rizatriptan (trade name Maxalt) is a...Ch. 17 - 17.61 Zolpidem (trade name Ambien) promotes the...Ch. 17 - 17.62 Answer the following questions about...Ch. 17 - 17.63 Stanozolol is an anabolic steroid that...Ch. 17 - Prob. 17.64PCh. 17 - 17.65 Use the observed data to decide whether C...Ch. 17 - Prob. 17.66PCh. 17 - Prob. 17.67PCh. 17 - Prob. 17.68PCh. 17 - 17.69 Although benzene itself absorbs at in its ...
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