Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 17, Problem 17.12P
Interpretation Introduction

(a)

Interpretation:

Whether the given compound gives the same product, different product or no reaction on oxidation with PCC and MnO2 is to be predicted.

Concept introduction:

The oxidizing agent PCC oxidizes primary alcohols to aldehyde and secondary alcohols to ketones. On the other hand, MnO2 is a selective oxidizing agent. It oxidizes allylic and benzylic hydrogens. Primary allylic alcohols are oxidized into aldehydes whereas secondary allylic alcohols are oxidized into ketones on treatment with MnO2.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound gives the same product, different product or no reaction on oxidation with PCC and MnO2 is to be predicted.

Concept introduction:

The oxidizing agent PCC oxidizes primary alcohols to aldehyde and secondary alcohols to ketones. On the other hand, MnO2 is a selective oxidizing agent. It oxidizes allylic and benzylic hydrogens. Primary allylic alcohols are oxidized into aldehydes whereas secondary allylic alcohols are oxidized into ketones on treatment with MnO2.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound gives the same product, different product or no reaction on oxidation with PCC and MnO2 is to be predicted.

Concept introduction:

The oxidizing agent PCC oxidizes primary alcohols to aldehyde and secondary alcohols to ketones. On the other hand, MnO2 is a selective oxidizing agent. It oxidizes allylic and benzylic hydrogens. Primary allylic alcohols are oxidized into aldehydes whereas secondary allylic alcohols are oxidized into ketones on treatment with MnO2.

Interpretation Introduction

(d)

Interpretation:

Whether the given compound gives the same product, different product or no reaction on oxidation with PCC and MnO2 is to be predicted.

Concept introduction:

The oxidizing agent PCC oxidizes primary alcohols to aldehyde and secondary alcohols to ketones. On the other hand, MnO2 is a selective oxidizing agent. It oxidizes allylic and benzylic hydrogens. Primary allylic alcohols are oxidized into aldehydes whereas secondary allylic alcohols are oxidized into ketones on treatment with MnO2.

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