Chemistry: The Central Science (14th Edition)
Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134414232
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 17, Problem 101AE

Salts containing the phosphate ion are added to municipal water supplies to prevent the corrosion of lead pipes.

  1. Based on the PK, values for phosphoric acid (Pka1 = 7.5 × 10-3 Pka2 = 6.2 × 10-8, pka3 = 4.2 × 10-13) what is the Kb value for the PO43- ion?
  2. What is the pH of a 1× 10-3 M solution of Na3PO4 (you can ignore the formation of H2PO4- and H3PO4)?

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Salts containing the phosphate ion are added to municipalwater supplies to prevent the corrosion of lead pipes. (a) Basedon the pKa values for phosphoric acid (pKa1 = 7.5 x 10 - 3,pKa2 = 6.2 x 10 - 8, pKa3 = 4.2 x 10 - 13) what is the Kbvalue for the PO43 - ion? (b) What is the pH of a 1 x 10 -3 M solution of Na3PO4 (you can ignore the formation ofH2PO4- and H3PO4)?
What is the concentration of CO32– in a 0.030 M solution of carbonic acid, H2CO3? For carbonic acid, Ka1 = 4.2  10–7and Ka2 = 4.8  10–11.
You need a buffer with a pH = 12. You have solid Na3PO4​and 1.00 M HCl, and water. The buffer must have a total phosphate concentration of 0.750 M and have a total volume of 500 mL. Calculate the amount of Na3PO4(in grams), the volume of 1.00 M HCl, and volume of water necessary to make the desired buffer. The pKa values of H3PO4 are pKa1=2.14, pKa2=7.20, pKa3=12.37 What are the Grams of Na3PO4

Chapter 17 Solutions

Chemistry: The Central Science (14th Edition)

Ch. 17.2 - Prob. 17.6.1PECh. 17.2 - Determine The pH of the original buffer described...Ch. 17.3 - An acid-base titration is performed: 250.0 mL of...Ch. 17.3 - Prob. 17.7.2PECh. 17.3 - Prob. 17.8.1PECh. 17.3 - Calculate the pH in the solution formed by adding...Ch. 17.3 - Prob. 17.9.1PECh. 17.3 - Prob. 17.9.2PECh. 17.4 - Which of these expressions correctly expresses the...Ch. 17.4 - Prob. 17.10.2PECh. 17.4 - You add 10.0 grams of solid copper(II) phosphate,...Ch. 17.4 - Prob. 17.11.2PECh. 17.4 - Prob. 17.12.1PECh. 17.4 - Prob. 17.12.2PECh. 17.5 - Consider a saturated solution of the salt MA3, in...Ch. 17.5 - Prob. 17.13.2PECh. 17.5 - Prob. 17.14.1PECh. 17.5 - Prob. 17.14.2PECh. 17.5 - Prob. 17.15.1PECh. 17.5 - Prob. 17.15.2PECh. 17.6 - An insoluble salt MA has a Kap of 1.0 × 10-10. Two...Ch. 17.6 - Does a precipitate form when 0.050 L of 2.0 × 10-2...Ch. 17.6 - Under what conditions does an ionic compound...Ch. 17.6 - Prob. 17.17.2PECh. 17 - Prob. 1DECh. 17 - The following boxes represent aqueos solutions...Ch. 17 - Prob. 2ECh. 17 - Prob. 3ECh. 17 - Prob. 4ECh. 17 - Prob. 5ECh. 17 - Prob. 6ECh. 17 - Prob. 7ECh. 17 - Prob. 8ECh. 17 - 17.9 The following graphs represent the behavior...Ch. 17 - Prob. 10ECh. 17 - 17.11 The graph below shows the solubility of a...Ch. 17 - 17.12 Three cations, Ni+2, Cu+2, and Ag+, are...Ch. 17 - Prob. 13ECh. 17 - Prob. 14ECh. 17 - Prob. 15ECh. 17 - Use information from Appendix D to calculate the...Ch. 17 - Prob. 17ECh. 17 - a. calculate the percent ionization of 0.125 M...Ch. 17 - Prob. 19ECh. 17 - 17.20 Which of the following solutions is a...Ch. 17 - Prob. 21ECh. 17 - Calculate the pH of a buffer that is 0.105n M in...Ch. 17 - Prob. 23ECh. 17 - A buffer is prepared by adding 10.0 g of ammonium...Ch. 17 - You are asked to prepare a pH = 3.00 buffer...Ch. 17 - You are asked to prepare an pH = 4.00 buffer...Ch. 17 - Prob. 27ECh. 17 - Prob. 28ECh. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - Prob. 31ECh. 17 - Prob. 32ECh. 17 - The accompanying graph shows the titration curves...Ch. 17 - Prob. 34ECh. 17 - 17.35 The samples of nitric and acetic acids shows...Ch. 17 - 17.36 Determine whether each of the following...Ch. 17 - Prob. 37ECh. 17 - Prob. 38ECh. 17 - Prob. 39ECh. 17 - Assume that 30.0 mL of a M solution of a week base...Ch. 17 - Prob. 41ECh. 17 - Prob. 42ECh. 17 - Prob. 43ECh. 17 - Prob. 44ECh. 17 - Prob. 45ECh. 17 - Consider the titration of 30.0 mL of 0.050 M NH3...Ch. 17 - Prob. 47ECh. 17 - Prob. 48ECh. 17 - 17.49 for each statement, incate whether it is...Ch. 17 - The solubility of two slighty soluble salts of...Ch. 17 - Prob. 51ECh. 17 - 17.52 a. true or false: solubility and...Ch. 17 - If the molar solubility CaF2 at 35 C is 1.24 *10-3...Ch. 17 - Prob. 54ECh. 17 - Prob. 55ECh. 17 - Prob. 56ECh. 17 - using calculate the molar solubility of AgBr in a....Ch. 17 - calculate the solubility of LaF3 in grams per...Ch. 17 - Prob. 59ECh. 17 - Consider a beaker containing a saturated solution...Ch. 17 - Calculate the solubility of Mn (OH) 2 in grams per...Ch. 17 - Calculate the molar solubility of Ni (OH) 2 when...Ch. 17 - 17.63 Which of the following salts will be...Ch. 17 - For each of the following slightly soluble salts,...Ch. 17 - Prob. 65ECh. 17 - Prob. 66ECh. 17 - Use values of Kap for Agl and Kf for Ag (CN) 2- to...Ch. 17 - Prob. 68ECh. 17 - Prob. 69ECh. 17 - Prob. 70ECh. 17 - Calculate the minimum pH needed to precipitate Mn...Ch. 17 - Prob. 72ECh. 17 - Prob. 73ECh. 17 - Prob. 74ECh. 17 - Prob. 75ECh. 17 - Prob. 76ECh. 17 - A solution containing several metal ions is...Ch. 17 - An unknown solid is entirely soluble in water. On...Ch. 17 - Prob. 79ECh. 17 - Prob. 80ECh. 17 - 17.81 Precipitation of the group 4 cautions of...Ch. 17 - Prob. 82ECh. 17 - Prob. 83AECh. 17 - Prob. 84AECh. 17 - Furoic acid (HC5H3O3) has a K value of 6.76 x 10-4...Ch. 17 - Prob. 86AECh. 17 - Equal quantities of 0.010 M solution of an acid HA...Ch. 17 - Prob. 88AECh. 17 - 17.89 A biochemist needs 750 ml of an acetic...Ch. 17 - A sample of 0.2140 g of an unknown monophonic acid...Ch. 17 - A sample of 0.1687 g of an unknown monoprotic acid...Ch. 17 - Prob. 92AECh. 17 - Prob. 93AECh. 17 - What is the pH of a solution made by mixing 0.30...Ch. 17 - Suppose you want to do a physiological experiment...Ch. 17 - Prob. 96AECh. 17 - Prob. 97AECh. 17 - For each pair of compounds, use Kap values to...Ch. 17 - Prob. 99AECh. 17 - Tooth enamel is composed of hydroxyapatite, whose...Ch. 17 - Salts containing the phosphate ion are added to...Ch. 17 - Prob. 102AECh. 17 - 17.103 The solubility –product constant for barium...Ch. 17 - Prob. 104AECh. 17 - Prob. 105AECh. 17 - A buffer of what pH is needed to give a Mg2+...Ch. 17 - The value of Kap for Mg3(AsO4)2 is 2.1 10-20 ....Ch. 17 - Prob. 108AECh. 17 - Prob. 109AECh. 17 - Prob. 110IECh. 17 - Prob. 111IECh. 17 - Prob. 112IECh. 17 - Prob. 113IECh. 17 - Prob. 114IECh. 17 - Prob. 115IECh. 17 - Prob. 116IECh. 17 - A concentration of 10-100 parts per billion (by...Ch. 17 - Prob. 118IECh. 17 - Prob. 119IECh. 17 - In nonaqueous solvents, it is possible to react HF...
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