a) Interpretation: Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated. Concept introduction: In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect. Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating. To state: Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

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Answer 1

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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need help please and thanks dont understand a-b Learning Goal: As discussed during the lecture, the enzyme HIV-1 reverse transcriptae (HIV-RT) plays a significant role for the HIV virus and is an important drug target. Assume a concentration [E] of 2.00 µM (i.e. 2.00 x 10-6 mol/l) for HIV-RT. Two potential drug molecules, D1 and D2, were identified, which form stable complexes with the HIV-RT. The dissociation constant of the complex ED1 formed by HIV-RT and the drug D1 is 1.00 nM (i.e. 1.00 x 10-9). The dissociation constant of the complex ED2 formed by HIV-RT and the drug D2 is 100 nM (i.e. 1.00 x 10-7). Part A - Difference in binding free eenergies Compute the difference in binding free energy (at a physiological temperature T=310 K) for the complexes. Provide the difference as a positive numerical expression with three significant figures in kJ/mol. The margin of error is 2%. Part B - Compare difference in free energy to the thermal energy Divide the…

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Answer 2

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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Answer 3

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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Answer 4

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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Answer 5

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

Answer 6

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Answer 7

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Answer 8

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 9

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 10

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 11

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 12

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

Answer 13

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

Answer 14

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Ch. 16.1 - Prob. 1P Ch. 16.2 - Propose a mechanism for the electrophilic...Ch. 16.2 - How many products might be formed on chlorination...Ch. 16.2 - When benzene is treated with D2SÅª4. deuterium...Ch. 16.3 - Prob. 5P Ch. 16.3 - What is the major monosubstitution product from...Ch. 16.3 - Identify the carboxylic acid chloride that might...Ch. 16.4 - Rank the compounds in each of the following groups...Ch. 16.4 - Predict the major products of the following...Ch. 16.4 - Prob. 10P

Chapter 16 Solutions